catena-Poly[cobalt(II)-di-μ-chlorido-κ(4) Cl:Cl-μ-1,5-dimethyl-1H-tetra­zole-κ(2) N (3):N (4)]: an X-ray powder investigation

The asymmetric unit of the title compound, [CoCl(2)(C(3)H(6)N(4))](n), contains two Co atoms, both lying on inversion centres, two Cl atoms and one 1,5-dimethyl­tetra­zole ligand. The coordination polyhedra of both Co atoms adopt flattened octa­hedral geometry, with two N atoms from two ligands in a...

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Autores principales: Ivashkevich, Ludmila S., Lyakhov, Alexander S., Mosalkova, Anastasiya P., Gaponik, Pavel N., Ivashkevich, Oleg A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968201/
https://www.ncbi.nlm.nih.gov/pubmed/21581826
http://dx.doi.org/10.1107/S1600536809003018
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author Ivashkevich, Ludmila S.
Lyakhov, Alexander S.
Mosalkova, Anastasiya P.
Gaponik, Pavel N.
Ivashkevich, Oleg A.
author_facet Ivashkevich, Ludmila S.
Lyakhov, Alexander S.
Mosalkova, Anastasiya P.
Gaponik, Pavel N.
Ivashkevich, Oleg A.
author_sort Ivashkevich, Ludmila S.
collection PubMed
description The asymmetric unit of the title compound, [CoCl(2)(C(3)H(6)N(4))](n), contains two Co atoms, both lying on inversion centres, two Cl atoms and one 1,5-dimethyl­tetra­zole ligand. The coordination polyhedra of both Co atoms adopt flattened octa­hedral geometry, with two N atoms from two ligands in axial positions and four Cl atoms in equatorial sites. Neighbouring Co atoms are linked together via two bridging Cl atoms and one tetra­zole ring to form polymeric chains running along the a axis.
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spelling pubmed-29682012010-12-30 catena-Poly[cobalt(II)-di-μ-chlorido-κ(4) Cl:Cl-μ-1,5-dimethyl-1H-tetra­zole-κ(2) N (3):N (4)]: an X-ray powder investigation Ivashkevich, Ludmila S. Lyakhov, Alexander S. Mosalkova, Anastasiya P. Gaponik, Pavel N. Ivashkevich, Oleg A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [CoCl(2)(C(3)H(6)N(4))](n), contains two Co atoms, both lying on inversion centres, two Cl atoms and one 1,5-dimethyl­tetra­zole ligand. The coordination polyhedra of both Co atoms adopt flattened octa­hedral geometry, with two N atoms from two ligands in axial positions and four Cl atoms in equatorial sites. Neighbouring Co atoms are linked together via two bridging Cl atoms and one tetra­zole ring to form polymeric chains running along the a axis. International Union of Crystallography 2009-01-28 /pmc/articles/PMC2968201/ /pubmed/21581826 http://dx.doi.org/10.1107/S1600536809003018 Text en © Ivashkevich et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ivashkevich, Ludmila S.
Lyakhov, Alexander S.
Mosalkova, Anastasiya P.
Gaponik, Pavel N.
Ivashkevich, Oleg A.
catena-Poly[cobalt(II)-di-μ-chlorido-κ(4) Cl:Cl-μ-1,5-dimethyl-1H-tetra­zole-κ(2) N (3):N (4)]: an X-ray powder investigation
title catena-Poly[cobalt(II)-di-μ-chlorido-κ(4) Cl:Cl-μ-1,5-dimethyl-1H-tetra­zole-κ(2) N (3):N (4)]: an X-ray powder investigation
title_full catena-Poly[cobalt(II)-di-μ-chlorido-κ(4) Cl:Cl-μ-1,5-dimethyl-1H-tetra­zole-κ(2) N (3):N (4)]: an X-ray powder investigation
title_fullStr catena-Poly[cobalt(II)-di-μ-chlorido-κ(4) Cl:Cl-μ-1,5-dimethyl-1H-tetra­zole-κ(2) N (3):N (4)]: an X-ray powder investigation
title_full_unstemmed catena-Poly[cobalt(II)-di-μ-chlorido-κ(4) Cl:Cl-μ-1,5-dimethyl-1H-tetra­zole-κ(2) N (3):N (4)]: an X-ray powder investigation
title_short catena-Poly[cobalt(II)-di-μ-chlorido-κ(4) Cl:Cl-μ-1,5-dimethyl-1H-tetra­zole-κ(2) N (3):N (4)]: an X-ray powder investigation
title_sort catena-poly[cobalt(ii)-di-μ-chlorido-κ(4) cl:cl-μ-1,5-dimethyl-1h-tetra­zole-κ(2) n (3):n (4)]: an x-ray powder investigation
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968201/
https://www.ncbi.nlm.nih.gov/pubmed/21581826
http://dx.doi.org/10.1107/S1600536809003018
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