catena-Poly[cobalt(II)-di-μ-chlorido-κ(4) Cl:Cl-μ-1,5-dimethyl-1H-tetrazole-κ(2) N (3):N (4)]: an X-ray powder investigation
The asymmetric unit of the title compound, [CoCl(2)(C(3)H(6)N(4))](n), contains two Co atoms, both lying on inversion centres, two Cl atoms and one 1,5-dimethyltetrazole ligand. The coordination polyhedra of both Co atoms adopt flattened octahedral geometry, with two N atoms from two ligands in a...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968201/ https://www.ncbi.nlm.nih.gov/pubmed/21581826 http://dx.doi.org/10.1107/S1600536809003018 |
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author | Ivashkevich, Ludmila S. Lyakhov, Alexander S. Mosalkova, Anastasiya P. Gaponik, Pavel N. Ivashkevich, Oleg A. |
author_facet | Ivashkevich, Ludmila S. Lyakhov, Alexander S. Mosalkova, Anastasiya P. Gaponik, Pavel N. Ivashkevich, Oleg A. |
author_sort | Ivashkevich, Ludmila S. |
collection | PubMed |
description | The asymmetric unit of the title compound, [CoCl(2)(C(3)H(6)N(4))](n), contains two Co atoms, both lying on inversion centres, two Cl atoms and one 1,5-dimethyltetrazole ligand. The coordination polyhedra of both Co atoms adopt flattened octahedral geometry, with two N atoms from two ligands in axial positions and four Cl atoms in equatorial sites. Neighbouring Co atoms are linked together via two bridging Cl atoms and one tetrazole ring to form polymeric chains running along the a axis. |
format | Text |
id | pubmed-2968201 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29682012010-12-30 catena-Poly[cobalt(II)-di-μ-chlorido-κ(4) Cl:Cl-μ-1,5-dimethyl-1H-tetrazole-κ(2) N (3):N (4)]: an X-ray powder investigation Ivashkevich, Ludmila S. Lyakhov, Alexander S. Mosalkova, Anastasiya P. Gaponik, Pavel N. Ivashkevich, Oleg A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [CoCl(2)(C(3)H(6)N(4))](n), contains two Co atoms, both lying on inversion centres, two Cl atoms and one 1,5-dimethyltetrazole ligand. The coordination polyhedra of both Co atoms adopt flattened octahedral geometry, with two N atoms from two ligands in axial positions and four Cl atoms in equatorial sites. Neighbouring Co atoms are linked together via two bridging Cl atoms and one tetrazole ring to form polymeric chains running along the a axis. International Union of Crystallography 2009-01-28 /pmc/articles/PMC2968201/ /pubmed/21581826 http://dx.doi.org/10.1107/S1600536809003018 Text en © Ivashkevich et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ivashkevich, Ludmila S. Lyakhov, Alexander S. Mosalkova, Anastasiya P. Gaponik, Pavel N. Ivashkevich, Oleg A. catena-Poly[cobalt(II)-di-μ-chlorido-κ(4) Cl:Cl-μ-1,5-dimethyl-1H-tetrazole-κ(2) N (3):N (4)]: an X-ray powder investigation |
title |
catena-Poly[cobalt(II)-di-μ-chlorido-κ(4)
Cl:Cl-μ-1,5-dimethyl-1H-tetrazole-κ(2)
N
(3):N
(4)]: an X-ray powder investigation |
title_full |
catena-Poly[cobalt(II)-di-μ-chlorido-κ(4)
Cl:Cl-μ-1,5-dimethyl-1H-tetrazole-κ(2)
N
(3):N
(4)]: an X-ray powder investigation |
title_fullStr |
catena-Poly[cobalt(II)-di-μ-chlorido-κ(4)
Cl:Cl-μ-1,5-dimethyl-1H-tetrazole-κ(2)
N
(3):N
(4)]: an X-ray powder investigation |
title_full_unstemmed |
catena-Poly[cobalt(II)-di-μ-chlorido-κ(4)
Cl:Cl-μ-1,5-dimethyl-1H-tetrazole-κ(2)
N
(3):N
(4)]: an X-ray powder investigation |
title_short |
catena-Poly[cobalt(II)-di-μ-chlorido-κ(4)
Cl:Cl-μ-1,5-dimethyl-1H-tetrazole-κ(2)
N
(3):N
(4)]: an X-ray powder investigation |
title_sort | catena-poly[cobalt(ii)-di-μ-chlorido-κ(4)
cl:cl-μ-1,5-dimethyl-1h-tetrazole-κ(2)
n
(3):n
(4)]: an x-ray powder investigation |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968201/ https://www.ncbi.nlm.nih.gov/pubmed/21581826 http://dx.doi.org/10.1107/S1600536809003018 |
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