[1,2-Bis(diphenyl­phosphino)ethane-κ(2) P,P′](2-carboxyl­atothio­phenolato-κ(2) O,S)nickel(II) methanol solvate

In the title complex, [Ni(C(7)H(4)O(2)S)(C(26)H(24)P(2))]·CH(3)OH, the nickel(II) centre adopts an approximately square-planar geometry, with the Ni atom coordinating to the S and O atoms of the bidentate thio­salicylate ligand and the two P atoms of the chelating Ph(2)PCH(2)CH(2)PPh(2) ligand. Ther...

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Detalles Bibliográficos
Autores principales: Miao, Jinling, Li, Furong, Chen, Haiyan, Wang, Daqi, Nie, Yong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968203/
https://www.ncbi.nlm.nih.gov/pubmed/21581768
http://dx.doi.org/10.1107/S1600536808044280
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author Miao, Jinling
Li, Furong
Chen, Haiyan
Wang, Daqi
Nie, Yong
author_facet Miao, Jinling
Li, Furong
Chen, Haiyan
Wang, Daqi
Nie, Yong
author_sort Miao, Jinling
collection PubMed
description In the title complex, [Ni(C(7)H(4)O(2)S)(C(26)H(24)P(2))]·CH(3)OH, the nickel(II) centre adopts an approximately square-planar geometry, with the Ni atom coordinating to the S and O atoms of the bidentate thio­salicylate ligand and the two P atoms of the chelating Ph(2)PCH(2)CH(2)PPh(2) ligand. There is hydrogen bonding between the methanol solvent mol­ecule and the carbonyl O atom of the thio­salicylate ligand.
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spelling pubmed-29682032010-12-30 [1,2-Bis(diphenyl­phosphino)ethane-κ(2) P,P′](2-carboxyl­atothio­phenolato-κ(2) O,S)nickel(II) methanol solvate Miao, Jinling Li, Furong Chen, Haiyan Wang, Daqi Nie, Yong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(7)H(4)O(2)S)(C(26)H(24)P(2))]·CH(3)OH, the nickel(II) centre adopts an approximately square-planar geometry, with the Ni atom coordinating to the S and O atoms of the bidentate thio­salicylate ligand and the two P atoms of the chelating Ph(2)PCH(2)CH(2)PPh(2) ligand. There is hydrogen bonding between the methanol solvent mol­ecule and the carbonyl O atom of the thio­salicylate ligand. International Union of Crystallography 2009-01-08 /pmc/articles/PMC2968203/ /pubmed/21581768 http://dx.doi.org/10.1107/S1600536808044280 Text en © Miao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Miao, Jinling
Li, Furong
Chen, Haiyan
Wang, Daqi
Nie, Yong
[1,2-Bis(diphenyl­phosphino)ethane-κ(2) P,P′](2-carboxyl­atothio­phenolato-κ(2) O,S)nickel(II) methanol solvate
title [1,2-Bis(diphenyl­phosphino)ethane-κ(2) P,P′](2-carboxyl­atothio­phenolato-κ(2) O,S)nickel(II) methanol solvate
title_full [1,2-Bis(diphenyl­phosphino)ethane-κ(2) P,P′](2-carboxyl­atothio­phenolato-κ(2) O,S)nickel(II) methanol solvate
title_fullStr [1,2-Bis(diphenyl­phosphino)ethane-κ(2) P,P′](2-carboxyl­atothio­phenolato-κ(2) O,S)nickel(II) methanol solvate
title_full_unstemmed [1,2-Bis(diphenyl­phosphino)ethane-κ(2) P,P′](2-carboxyl­atothio­phenolato-κ(2) O,S)nickel(II) methanol solvate
title_short [1,2-Bis(diphenyl­phosphino)ethane-κ(2) P,P′](2-carboxyl­atothio­phenolato-κ(2) O,S)nickel(II) methanol solvate
title_sort [1,2-bis(diphenyl­phosphino)ethane-κ(2) p,p′](2-carboxyl­atothio­phenolato-κ(2) o,s)nickel(ii) methanol solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968203/
https://www.ncbi.nlm.nih.gov/pubmed/21581768
http://dx.doi.org/10.1107/S1600536808044280
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AT lifurong 12bisdiphenylphosphinoethanek2pp2carboxylatothiophenolatok2osnickeliimethanolsolvate
AT chenhaiyan 12bisdiphenylphosphinoethanek2pp2carboxylatothiophenolatok2osnickeliimethanolsolvate
AT wangdaqi 12bisdiphenylphosphinoethanek2pp2carboxylatothiophenolatok2osnickeliimethanolsolvate
AT nieyong 12bisdiphenylphosphinoethanek2pp2carboxylatothiophenolatok2osnickeliimethanolsolvate

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