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1,3-Bis(2-thienylmethyl)-4,5-dihydroimidazolium trichlorido(η(6)-p-cymene)ruthenate(II)
The asymmetric unit of the title compound, (C(13)H(15)N(2)S(2))[RuCl(3)(C(10)H(14))], contains a 1,3-(2-thienylmethyl)-4,5-dihydroimidazolium cation and a trichlorido(η (6)-p-cymene)ruthenate(II) anion. The thiophene rings of the cation are disordered by an 180° rotation about the thiophene–CH(2...
Autores principales: | , , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968218/ https://www.ncbi.nlm.nih.gov/pubmed/21581774 http://dx.doi.org/10.1107/S1600536809000464 |
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author | Arslan, Hakan VanDerveer, Don Özdemir, İsmail Gürbüz, Nevin Gök, Yetkin Çetinkaya, Bekir |
author_facet | Arslan, Hakan VanDerveer, Don Özdemir, İsmail Gürbüz, Nevin Gök, Yetkin Çetinkaya, Bekir |
author_sort | Arslan, Hakan |
collection | PubMed |
description | The asymmetric unit of the title compound, (C(13)H(15)N(2)S(2))[RuCl(3)(C(10)H(14))], contains a 1,3-(2-thienylmethyl)-4,5-dihydroimidazolium cation and a trichlorido(η (6)-p-cymene)ruthenate(II) anion. The thiophene rings of the cation are disordered by an 180° rotation about the thiophene–CH(2) bonds with occupancies of 0.847 (5)/0.153 (5) and 0.700 (5)/0.300 (5), respectively. The Ru atom exhibits a distorted octahedral coordination with the benzene ring of the p-cymene ligand formally occupying three sites and three Cl atoms occupying the other three sites. The short C—N bond lengths in the imidazoline ring indicate partial electron delocalization within the N—C—N fragment. Cation and anions are connected through five intermolecular C—H⋯Cl hydrogen bonds and one C—H⋯π hydrogen bond, forming a three-dimensional hydrogen-bonded network. |
format | Text |
id | pubmed-2968218 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29682182010-12-30 1,3-Bis(2-thienylmethyl)-4,5-dihydroimidazolium trichlorido(η(6)-p-cymene)ruthenate(II) Arslan, Hakan VanDerveer, Don Özdemir, İsmail Gürbüz, Nevin Gök, Yetkin Çetinkaya, Bekir Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(13)H(15)N(2)S(2))[RuCl(3)(C(10)H(14))], contains a 1,3-(2-thienylmethyl)-4,5-dihydroimidazolium cation and a trichlorido(η (6)-p-cymene)ruthenate(II) anion. The thiophene rings of the cation are disordered by an 180° rotation about the thiophene–CH(2) bonds with occupancies of 0.847 (5)/0.153 (5) and 0.700 (5)/0.300 (5), respectively. The Ru atom exhibits a distorted octahedral coordination with the benzene ring of the p-cymene ligand formally occupying three sites and three Cl atoms occupying the other three sites. The short C—N bond lengths in the imidazoline ring indicate partial electron delocalization within the N—C—N fragment. Cation and anions are connected through five intermolecular C—H⋯Cl hydrogen bonds and one C—H⋯π hydrogen bond, forming a three-dimensional hydrogen-bonded network. International Union of Crystallography 2009-01-10 /pmc/articles/PMC2968218/ /pubmed/21581774 http://dx.doi.org/10.1107/S1600536809000464 Text en © Arslan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Arslan, Hakan VanDerveer, Don Özdemir, İsmail Gürbüz, Nevin Gök, Yetkin Çetinkaya, Bekir 1,3-Bis(2-thienylmethyl)-4,5-dihydroimidazolium trichlorido(η(6)-p-cymene)ruthenate(II) |
title | 1,3-Bis(2-thienylmethyl)-4,5-dihydroimidazolium trichlorido(η(6)-p-cymene)ruthenate(II) |
title_full | 1,3-Bis(2-thienylmethyl)-4,5-dihydroimidazolium trichlorido(η(6)-p-cymene)ruthenate(II) |
title_fullStr | 1,3-Bis(2-thienylmethyl)-4,5-dihydroimidazolium trichlorido(η(6)-p-cymene)ruthenate(II) |
title_full_unstemmed | 1,3-Bis(2-thienylmethyl)-4,5-dihydroimidazolium trichlorido(η(6)-p-cymene)ruthenate(II) |
title_short | 1,3-Bis(2-thienylmethyl)-4,5-dihydroimidazolium trichlorido(η(6)-p-cymene)ruthenate(II) |
title_sort | 1,3-bis(2-thienylmethyl)-4,5-dihydroimidazolium trichlorido(η(6)-p-cymene)ruthenate(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968218/ https://www.ncbi.nlm.nih.gov/pubmed/21581774 http://dx.doi.org/10.1107/S1600536809000464 |
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