Low-temperature redetermination of tribenzyl­chloridotin(IV)

Compared to the previous studies [Ng (1997 ▶). Acta Cryst. C53, 56–58; Yin et al. (2005 ▶). Huaxue Shiji, 27, 295–296], the redetermined structure of the title compound, [Sn(C(7)H(7))(3)Cl], exhibits a doubled c unit-cell parameter. There are two mol­ecules in the asymmetric unit, with both Sn and b...

Descripción completa

Detalles Bibliográficos
Autor principal: Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968220/
https://www.ncbi.nlm.nih.gov/pubmed/21581828
http://dx.doi.org/10.1107/S160053680900289X
Descripción
Sumario:Compared to the previous studies [Ng (1997 ▶). Acta Cryst. C53, 56–58; Yin et al. (2005 ▶). Huaxue Shiji, 27, 295–296], the redetermined structure of the title compound, [Sn(C(7)H(7))(3)Cl], exhibits a doubled c unit-cell parameter. There are two mol­ecules in the asymmetric unit, with both Sn and both Cl atoms having 3 site symmetry. The Sn atoms have distorted SnClC(3) tetra­hedral geometries and the mol­ecules inter­act by way of short Sn⋯Cl bridges [Sn⋯Cl = 3.418 (2) and 3.475 (2) Å], thereby forming chains propagating in c.

Ejemplares similares