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Low-temperature redetermination of tribenzylchloridotin(IV)
Compared to the previous studies [Ng (1997 ▶). Acta Cryst. C53, 56–58; Yin et al. (2005 ▶). Huaxue Shiji, 27, 295–296], the redetermined structure of the title compound, [Sn(C(7)H(7))(3)Cl], exhibits a doubled c unit-cell parameter. There are two molecules in the asymmetric unit, with both Sn and b...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968220/ https://www.ncbi.nlm.nih.gov/pubmed/21581828 http://dx.doi.org/10.1107/S160053680900289X |
| _version_ | 1782189809393991680 |
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| author | Ng, Seik Weng |
| author_facet | Ng, Seik Weng |
| author_sort | Ng, Seik Weng |
| collection | PubMed |
| description | Compared to the previous studies [Ng (1997 ▶). Acta Cryst. C53, 56–58; Yin et al. (2005 ▶). Huaxue Shiji, 27, 295–296], the redetermined structure of the title compound, [Sn(C(7)H(7))(3)Cl], exhibits a doubled c unit-cell parameter. There are two molecules in the asymmetric unit, with both Sn and both Cl atoms having 3 site symmetry. The Sn atoms have distorted SnClC(3) tetrahedral geometries and the molecules interact by way of short Sn⋯Cl bridges [Sn⋯Cl = 3.418 (2) and 3.475 (2) Å], thereby forming chains propagating in c. |
| format | Text |
| id | pubmed-2968220 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29682202010-12-30 Low-temperature redetermination of tribenzylchloridotin(IV) Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Compared to the previous studies [Ng (1997 ▶). Acta Cryst. C53, 56–58; Yin et al. (2005 ▶). Huaxue Shiji, 27, 295–296], the redetermined structure of the title compound, [Sn(C(7)H(7))(3)Cl], exhibits a doubled c unit-cell parameter. There are two molecules in the asymmetric unit, with both Sn and both Cl atoms having 3 site symmetry. The Sn atoms have distorted SnClC(3) tetrahedral geometries and the molecules interact by way of short Sn⋯Cl bridges [Sn⋯Cl = 3.418 (2) and 3.475 (2) Å], thereby forming chains propagating in c. International Union of Crystallography 2009-01-28 /pmc/articles/PMC2968220/ /pubmed/21581828 http://dx.doi.org/10.1107/S160053680900289X Text en © Seik Weng Ng 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ng, Seik Weng Low-temperature redetermination of tribenzylchloridotin(IV) |
| title | Low-temperature redetermination of tribenzylchloridotin(IV) |
| title_full | Low-temperature redetermination of tribenzylchloridotin(IV) |
| title_fullStr | Low-temperature redetermination of tribenzylchloridotin(IV) |
| title_full_unstemmed | Low-temperature redetermination of tribenzylchloridotin(IV) |
| title_short | Low-temperature redetermination of tribenzylchloridotin(IV) |
| title_sort | low-temperature redetermination of tribenzylchloridotin(iv) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968220/ https://www.ncbi.nlm.nih.gov/pubmed/21581828 http://dx.doi.org/10.1107/S160053680900289X |
| work_keys_str_mv | AT ngseikweng lowtemperatureredeterminationoftribenzylchloridotiniv |