Dichloridobis(phenyl 2-pyridyl ketone oxime)nickel(II) acetone solvate

The Ni atom in the title compound, [NiCl(2)(C(12)H(10)N(2)O)(2)]·C(3)H(6)O, adopts a distorted octa­hedral geometry, being ligated by four N atoms from two different phenyl 2-pyridyl ketone oxime ligands and two Cl atoms. In the crystal structure, inter­molecular O—H⋯Cl hydrogen bonds link the mol­e...

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Detalles Bibliográficos
Autores principales: Yin, Jing-Zhou, Liu, Guang-Xiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968227/
https://www.ncbi.nlm.nih.gov/pubmed/21581767
http://dx.doi.org/10.1107/S1600536808043961
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author Yin, Jing-Zhou
Liu, Guang-Xiang
author_facet Yin, Jing-Zhou
Liu, Guang-Xiang
author_sort Yin, Jing-Zhou
collection PubMed
description The Ni atom in the title compound, [NiCl(2)(C(12)H(10)N(2)O)(2)]·C(3)H(6)O, adopts a distorted octa­hedral geometry, being ligated by four N atoms from two different phenyl 2-pyridyl ketone oxime ligands and two Cl atoms. In the crystal structure, inter­molecular O—H⋯Cl hydrogen bonds link the mol­ecules into a chain structure along [010]. There is a π–π contact between the pyridine rings [centroid–centroid distance = 3.824 (5) Å].
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spelling pubmed-29682272010-12-30 Dichloridobis(phenyl 2-pyridyl ketone oxime)nickel(II) acetone solvate Yin, Jing-Zhou Liu, Guang-Xiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Ni atom in the title compound, [NiCl(2)(C(12)H(10)N(2)O)(2)]·C(3)H(6)O, adopts a distorted octa­hedral geometry, being ligated by four N atoms from two different phenyl 2-pyridyl ketone oxime ligands and two Cl atoms. In the crystal structure, inter­molecular O—H⋯Cl hydrogen bonds link the mol­ecules into a chain structure along [010]. There is a π–π contact between the pyridine rings [centroid–centroid distance = 3.824 (5) Å]. International Union of Crystallography 2009-01-08 /pmc/articles/PMC2968227/ /pubmed/21581767 http://dx.doi.org/10.1107/S1600536808043961 Text en © Yin and Liu 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yin, Jing-Zhou
Liu, Guang-Xiang
Dichloridobis(phenyl 2-pyridyl ketone oxime)nickel(II) acetone solvate
title Dichloridobis(phenyl 2-pyridyl ketone oxime)nickel(II) acetone solvate
title_full Dichloridobis(phenyl 2-pyridyl ketone oxime)nickel(II) acetone solvate
title_fullStr Dichloridobis(phenyl 2-pyridyl ketone oxime)nickel(II) acetone solvate
title_full_unstemmed Dichloridobis(phenyl 2-pyridyl ketone oxime)nickel(II) acetone solvate
title_short Dichloridobis(phenyl 2-pyridyl ketone oxime)nickel(II) acetone solvate
title_sort dichloridobis(phenyl 2-pyridyl ketone oxime)nickel(ii) acetone solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968227/
https://www.ncbi.nlm.nih.gov/pubmed/21581767
http://dx.doi.org/10.1107/S1600536808043961
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AT liuguangxiang dichloridobisphenyl2pyridylketoneoximenickeliiacetonesolvate

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