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cis-[Aqua/methanol(0.45/1.55)](1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato)nickel(II)–cis-[aqua/methanol(1.49/0.51)](1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato)nickel(II) (1/1)
The title compound, [Ni(C(8)H(10)F(3)O(2))(2)(CH(4)O)(1.55)(H(2)O)(0.45)][Ni(C(8)H(10)F(3)O(2))(2)(CH(4)O)(0.51)(H(2)O)(1.49)], is an octahedral nickel(II) complex with two acetylacetonate-like 1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionate ligands. The two chelating ligands are in cis positions...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968228/ https://www.ncbi.nlm.nih.gov/pubmed/21581813 http://dx.doi.org/10.1107/S1600536809001846 |
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author | Hunter, Gerald O. Zeller, Matthias Leskiw, Brian D. |
author_facet | Hunter, Gerald O. Zeller, Matthias Leskiw, Brian D. |
author_sort | Hunter, Gerald O. |
collection | PubMed |
description | The title compound, [Ni(C(8)H(10)F(3)O(2))(2)(CH(4)O)(1.55)(H(2)O)(0.45)][Ni(C(8)H(10)F(3)O(2))(2)(CH(4)O)(0.51)(H(2)O)(1.49)], is an octahedral nickel(II) complex with two acetylacetonate-like 1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionate ligands. The two chelating ligands are in cis positions with respect to each other and the remaining two adjacent coordination sites are taken up by water and methanol donor molecules. In both crystallographically independent molecules, each donor site shows disorder of methanol and water with occupancies of 0.51 (1) and 0.55 (1) in favor of methanol. The remaining two donor sites are not disordered and are water for the first and methanol for the second independent molecule. Rotational disorder is observed for one of the tert-butyl groups, the occupancy rate for the major component here is 0.687 (9). O—H⋯O hydrogen bonds connect the two independent molecules with each other and, across a crystallographic inversion center, they are combined with two neighboring molecules to form a centrosymmetric hydrogen-bonded tetramer. |
format | Text |
id | pubmed-2968228 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29682282010-12-30 cis-[Aqua/methanol(0.45/1.55)](1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato)nickel(II)–cis-[aqua/methanol(1.49/0.51)](1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato)nickel(II) (1/1) Hunter, Gerald O. Zeller, Matthias Leskiw, Brian D. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(C(8)H(10)F(3)O(2))(2)(CH(4)O)(1.55)(H(2)O)(0.45)][Ni(C(8)H(10)F(3)O(2))(2)(CH(4)O)(0.51)(H(2)O)(1.49)], is an octahedral nickel(II) complex with two acetylacetonate-like 1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionate ligands. The two chelating ligands are in cis positions with respect to each other and the remaining two adjacent coordination sites are taken up by water and methanol donor molecules. In both crystallographically independent molecules, each donor site shows disorder of methanol and water with occupancies of 0.51 (1) and 0.55 (1) in favor of methanol. The remaining two donor sites are not disordered and are water for the first and methanol for the second independent molecule. Rotational disorder is observed for one of the tert-butyl groups, the occupancy rate for the major component here is 0.687 (9). O—H⋯O hydrogen bonds connect the two independent molecules with each other and, across a crystallographic inversion center, they are combined with two neighboring molecules to form a centrosymmetric hydrogen-bonded tetramer. International Union of Crystallography 2009-01-23 /pmc/articles/PMC2968228/ /pubmed/21581813 http://dx.doi.org/10.1107/S1600536809001846 Text en © Hunter et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Hunter, Gerald O. Zeller, Matthias Leskiw, Brian D. cis-[Aqua/methanol(0.45/1.55)](1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato)nickel(II)–cis-[aqua/methanol(1.49/0.51)](1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato)nickel(II) (1/1) |
title |
cis-[Aqua/methanol(0.45/1.55)](1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato)nickel(II)–cis-[aqua/methanol(1.49/0.51)](1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato)nickel(II) (1/1) |
title_full |
cis-[Aqua/methanol(0.45/1.55)](1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato)nickel(II)–cis-[aqua/methanol(1.49/0.51)](1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato)nickel(II) (1/1) |
title_fullStr |
cis-[Aqua/methanol(0.45/1.55)](1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato)nickel(II)–cis-[aqua/methanol(1.49/0.51)](1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato)nickel(II) (1/1) |
title_full_unstemmed |
cis-[Aqua/methanol(0.45/1.55)](1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato)nickel(II)–cis-[aqua/methanol(1.49/0.51)](1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato)nickel(II) (1/1) |
title_short |
cis-[Aqua/methanol(0.45/1.55)](1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato)nickel(II)–cis-[aqua/methanol(1.49/0.51)](1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato)nickel(II) (1/1) |
title_sort | cis-[aqua/methanol(0.45/1.55)](1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato)nickel(ii)–cis-[aqua/methanol(1.49/0.51)](1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato)nickel(ii) (1/1) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968228/ https://www.ncbi.nlm.nih.gov/pubmed/21581813 http://dx.doi.org/10.1107/S1600536809001846 |
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