(4-Methoxy­benzoyl­meth­yl)triphenyl­phospho­nium trifluoro­methane­sulfonate

Colourless crystals of the title compound, C(27)H(24)O(2)P(+)·CF(3)SO(3) (−), have been prepared by the addition of a solution of AgCF(3)SO(3) in methanol to a solution of (4-methoxy­benzoyl­meth­yl)triphenyl­phospho­nium bromide in dry methanol. There are two crystallographically independent mol­ec...

Descripción completa

Detalles Bibliográficos
Autores principales: Karami, Kazem, Büyükgüngör, Orhan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968230/
https://www.ncbi.nlm.nih.gov/pubmed/21581906
http://dx.doi.org/10.1107/S1600536809000919
_version_ 1782189812429619200
author Karami, Kazem
Büyükgüngör, Orhan
author_facet Karami, Kazem
Büyükgüngör, Orhan
author_sort Karami, Kazem
collection PubMed
description Colourless crystals of the title compound, C(27)H(24)O(2)P(+)·CF(3)SO(3) (−), have been prepared by the addition of a solution of AgCF(3)SO(3) in methanol to a solution of (4-methoxy­benzoyl­meth­yl)triphenyl­phospho­nium bromide in dry methanol. There are two crystallographically independent mol­ecules in the asymmetric unit. The crystal structure is stabilized by inter- and intra­molecular C—H⋯O hydrogen bonds and further stabilized by C—H⋯π inter­actions.
format Text
id pubmed-2968230
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29682302010-12-30 (4-Methoxy­benzoyl­meth­yl)triphenyl­phospho­nium trifluoro­methane­sulfonate Karami, Kazem Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Organic Papers Colourless crystals of the title compound, C(27)H(24)O(2)P(+)·CF(3)SO(3) (−), have been prepared by the addition of a solution of AgCF(3)SO(3) in methanol to a solution of (4-methoxy­benzoyl­meth­yl)triphenyl­phospho­nium bromide in dry methanol. There are two crystallographically independent mol­ecules in the asymmetric unit. The crystal structure is stabilized by inter- and intra­molecular C—H⋯O hydrogen bonds and further stabilized by C—H⋯π inter­actions. International Union of Crystallography 2009-01-14 /pmc/articles/PMC2968230/ /pubmed/21581906 http://dx.doi.org/10.1107/S1600536809000919 Text en © Karami and Büyükgüngör 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Karami, Kazem
Büyükgüngör, Orhan
(4-Methoxy­benzoyl­meth­yl)triphenyl­phospho­nium trifluoro­methane­sulfonate
title (4-Methoxy­benzoyl­meth­yl)triphenyl­phospho­nium trifluoro­methane­sulfonate
title_full (4-Methoxy­benzoyl­meth­yl)triphenyl­phospho­nium trifluoro­methane­sulfonate
title_fullStr (4-Methoxy­benzoyl­meth­yl)triphenyl­phospho­nium trifluoro­methane­sulfonate
title_full_unstemmed (4-Methoxy­benzoyl­meth­yl)triphenyl­phospho­nium trifluoro­methane­sulfonate
title_short (4-Methoxy­benzoyl­meth­yl)triphenyl­phospho­nium trifluoro­methane­sulfonate
title_sort (4-methoxy­benzoyl­meth­yl)triphenyl­phospho­nium trifluoro­methane­sulfonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968230/
https://www.ncbi.nlm.nih.gov/pubmed/21581906
http://dx.doi.org/10.1107/S1600536809000919
work_keys_str_mv AT karamikazem 4methoxybenzoylmethyltriphenylphosphoniumtrifluoromethanesulfonate
AT buyukgungororhan 4methoxybenzoylmethyltriphenylphosphoniumtrifluoromethanesulfonate

Ejemplares similares