Hexakis(1-methyl-1H-imidazole-κN (3))cobalt(II) dibromide dihydrate

The asymmetric unit of the title compound, [Co(C(4)H(6)N(2))(6)]Br(2)·2H(2)O, contains one-half of the centrosymmetric cation, one Br atom and one water mol­ecule. The Co(II) atom, lying on an inversion center, has a distorted octa­hedral geometry, defined by six N atoms from six 1-methyl­imidazole...

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Autor principal: Yao, Rufu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968233/
https://www.ncbi.nlm.nih.gov/pubmed/21581762
http://dx.doi.org/10.1107/S1600536808042906
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author Yao, Rufu
author_facet Yao, Rufu
author_sort Yao, Rufu
collection PubMed
description The asymmetric unit of the title compound, [Co(C(4)H(6)N(2))(6)]Br(2)·2H(2)O, contains one-half of the centrosymmetric cation, one Br atom and one water mol­ecule. The Co(II) atom, lying on an inversion center, has a distorted octa­hedral geometry, defined by six N atoms from six 1-methyl­imidazole ligands. In the crystal structure, intra- and inter­molecular O—H⋯Br hydrogen bonds link pairs of uncoordinated water mol­ecules and bromide anions.
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spelling pubmed-29682332010-12-30 Hexakis(1-methyl-1H-imidazole-κN (3))cobalt(II) dibromide dihydrate Yao, Rufu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Co(C(4)H(6)N(2))(6)]Br(2)·2H(2)O, contains one-half of the centrosymmetric cation, one Br atom and one water mol­ecule. The Co(II) atom, lying on an inversion center, has a distorted octa­hedral geometry, defined by six N atoms from six 1-methyl­imidazole ligands. In the crystal structure, intra- and inter­molecular O—H⋯Br hydrogen bonds link pairs of uncoordinated water mol­ecules and bromide anions. International Union of Crystallography 2009-01-08 /pmc/articles/PMC2968233/ /pubmed/21581762 http://dx.doi.org/10.1107/S1600536808042906 Text en © Rufu Yao 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yao, Rufu
Hexakis(1-methyl-1H-imidazole-κN (3))cobalt(II) dibromide dihydrate
title Hexakis(1-methyl-1H-imidazole-κN (3))cobalt(II) dibromide dihydrate
title_full Hexakis(1-methyl-1H-imidazole-κN (3))cobalt(II) dibromide dihydrate
title_fullStr Hexakis(1-methyl-1H-imidazole-κN (3))cobalt(II) dibromide dihydrate
title_full_unstemmed Hexakis(1-methyl-1H-imidazole-κN (3))cobalt(II) dibromide dihydrate
title_short Hexakis(1-methyl-1H-imidazole-κN (3))cobalt(II) dibromide dihydrate
title_sort hexakis(1-methyl-1h-imidazole-κn (3))cobalt(ii) dibromide dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968233/
https://www.ncbi.nlm.nih.gov/pubmed/21581762
http://dx.doi.org/10.1107/S1600536808042906
work_keys_str_mv AT yaorufu hexakis1methyl1himidazolekn3cobaltiidibromidedihydrate

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