7-(2,2-Dimethylpropanamido)-2-methyl-1,8-naphthyridin-1-ium chloride monohydrate

The asymmetric unit of the title compound, C(14)H(18)N(3)O(+)·Cl(−)·H(2)O, comprises a substituted amido–naphthyridine cation, a chloride anion and a water mol­ecule of crystallization. Intra­molecular C—H⋯O hydrogen bonds generate six-membered rings, producing an S(6) ring motif. The amido group is...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Kia, Reza, Das, Nirmal Kumar, Sen, Debabrata, Goswami, Shyamaprosad
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968242/
https://www.ncbi.nlm.nih.gov/pubmed/21581941
http://dx.doi.org/10.1107/S1600536808042955
Descripción
Sumario:The asymmetric unit of the title compound, C(14)H(18)N(3)O(+)·Cl(−)·H(2)O, comprises a substituted amido–naphthyridine cation, a chloride anion and a water mol­ecule of crystallization. Intra­molecular C—H⋯O hydrogen bonds generate six-membered rings, producing an S(6) ring motif. The amido group is twisted from the naphthyridine ring, making a dihedral angle of 17.65 (7)°. The crystal structure is stabilized by inter­molecular N—H⋯O, N—H⋯Cl, O—H⋯Cl (× 2), and C—H⋯O (× 2) hydrogen bonds. These inter­actions linked neighbouring mol­ecules into chains along the a and b axes of the crystal, thus forming mol­ecular sheets parallel to the (001) plane.

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