7-(2,2-Dimethylpropanamido)-2-methyl-1,8-naphthyridin-1-ium chloride monohydrate

The asymmetric unit of the title compound, C(14)H(18)N(3)O(+)·Cl(−)·H(2)O, comprises a substituted amido–naphthyridine cation, a chloride anion and a water mol­ecule of crystallization. Intra­molecular C—H⋯O hydrogen bonds generate six-membered rings, producing an S(6) ring motif. The amido group is...

Descripción completa

Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Kia, Reza, Das, Nirmal Kumar, Sen, Debabrata, Goswami, Shyamaprosad
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968242/
https://www.ncbi.nlm.nih.gov/pubmed/21581941
http://dx.doi.org/10.1107/S1600536808042955
_version_ 1782189816503336960
author Fun, Hoong-Kun
Kia, Reza
Das, Nirmal Kumar
Sen, Debabrata
Goswami, Shyamaprosad
author_facet Fun, Hoong-Kun
Kia, Reza
Das, Nirmal Kumar
Sen, Debabrata
Goswami, Shyamaprosad
author_sort Fun, Hoong-Kun
collection PubMed
description The asymmetric unit of the title compound, C(14)H(18)N(3)O(+)·Cl(−)·H(2)O, comprises a substituted amido–naphthyridine cation, a chloride anion and a water mol­ecule of crystallization. Intra­molecular C—H⋯O hydrogen bonds generate six-membered rings, producing an S(6) ring motif. The amido group is twisted from the naphthyridine ring, making a dihedral angle of 17.65 (7)°. The crystal structure is stabilized by inter­molecular N—H⋯O, N—H⋯Cl, O—H⋯Cl (× 2), and C—H⋯O (× 2) hydrogen bonds. These inter­actions linked neighbouring mol­ecules into chains along the a and b axes of the crystal, thus forming mol­ecular sheets parallel to the (001) plane.
format Text
id pubmed-2968242
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29682422010-12-30 7-(2,2-Dimethylpropanamido)-2-methyl-1,8-naphthyridin-1-ium chloride monohydrate Fun, Hoong-Kun Kia, Reza Das, Nirmal Kumar Sen, Debabrata Goswami, Shyamaprosad Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(14)H(18)N(3)O(+)·Cl(−)·H(2)O, comprises a substituted amido–naphthyridine cation, a chloride anion and a water mol­ecule of crystallization. Intra­molecular C—H⋯O hydrogen bonds generate six-membered rings, producing an S(6) ring motif. The amido group is twisted from the naphthyridine ring, making a dihedral angle of 17.65 (7)°. The crystal structure is stabilized by inter­molecular N—H⋯O, N—H⋯Cl, O—H⋯Cl (× 2), and C—H⋯O (× 2) hydrogen bonds. These inter­actions linked neighbouring mol­ecules into chains along the a and b axes of the crystal, thus forming mol­ecular sheets parallel to the (001) plane. International Union of Crystallography 2009-01-17 /pmc/articles/PMC2968242/ /pubmed/21581941 http://dx.doi.org/10.1107/S1600536808042955 Text en © Fun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Kia, Reza
Das, Nirmal Kumar
Sen, Debabrata
Goswami, Shyamaprosad
7-(2,2-Dimethylpropanamido)-2-methyl-1,8-naphthyridin-1-ium chloride monohydrate
title 7-(2,2-Dimethylpropanamido)-2-methyl-1,8-naphthyridin-1-ium chloride monohydrate
title_full 7-(2,2-Dimethylpropanamido)-2-methyl-1,8-naphthyridin-1-ium chloride monohydrate
title_fullStr 7-(2,2-Dimethylpropanamido)-2-methyl-1,8-naphthyridin-1-ium chloride monohydrate
title_full_unstemmed 7-(2,2-Dimethylpropanamido)-2-methyl-1,8-naphthyridin-1-ium chloride monohydrate
title_short 7-(2,2-Dimethylpropanamido)-2-methyl-1,8-naphthyridin-1-ium chloride monohydrate
title_sort 7-(2,2-dimethylpropanamido)-2-methyl-1,8-naphthyridin-1-ium chloride monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968242/
https://www.ncbi.nlm.nih.gov/pubmed/21581941
http://dx.doi.org/10.1107/S1600536808042955
work_keys_str_mv AT funhoongkun 722dimethylpropanamido2methyl18naphthyridin1iumchloridemonohydrate
AT kiareza 722dimethylpropanamido2methyl18naphthyridin1iumchloridemonohydrate
AT dasnirmalkumar 722dimethylpropanamido2methyl18naphthyridin1iumchloridemonohydrate
AT sendebabrata 722dimethylpropanamido2methyl18naphthyridin1iumchloridemonohydrate
AT goswamishyamaprosad 722dimethylpropanamido2methyl18naphthyridin1iumchloridemonohydrate

Ejemplares similares