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Butyl 2-(5-bromo-3-methyl­sulfinyl-1-benzofuran-2-yl)acetate

In the title compound, C(15)H(17)BrO(4)S, the methyl­sulfinyl O atom and the methyl substituents lie on opposite sides of the plane through the benzofuran fragment. The crystal structure is stabilized by π–π inter­actions between the benzene rings of neighbouring mol­ecules [centroid–centroid distan...

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Detalles Bibliográficos
Autores principales: Choi, Hong Dae, Seo, Pil Ja, Son, Byeng Wha, Lee, Uk
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968244/
https://www.ncbi.nlm.nih.gov/pubmed/21581880
http://dx.doi.org/10.1107/S1600536808043985
Descripción
Sumario:In the title compound, C(15)H(17)BrO(4)S, the methyl­sulfinyl O atom and the methyl substituents lie on opposite sides of the plane through the benzofuran fragment. The crystal structure is stabilized by π–π inter­actions between the benzene rings of neighbouring mol­ecules [centroid–centroid distance = 3.698 (4) Å], and by C—H⋯π inter­actions between a methyl­ene H atom of the butyl group and the benzene ring of the benzofuran system. Additionally, the crystal structure exhibits weak inter­molecular C—H⋯O contacts. The butyl group is disordered over two positions, with site-occupancy factors, from refinement, of 0.720 (8) and 0.280 (8).