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Tris(2,2′-bipyridyl-κ(2) N,N′)copper(II) sulfate 7.5-hydrate
The title compound, [Cu(C(10)H(8)N(2))(3)]SO(4)·7.5H(2)O, is a six-coordinate copper(II) complex with a slightly elongated octahedral coordination geometry. The pyridyl rings of the three bipyridyl ligands are not coplanar, making dihedral angels of 9.5 (5), 5.2 (4) and 5.8 (5)°. In the crystal, se...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968254/ https://www.ncbi.nlm.nih.gov/pubmed/21581747 http://dx.doi.org/10.1107/S1600536808043821 |
| _version_ | 1782189819985657856 |
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| author | Xu, Feng You, Wei Huang, Wei |
| author_facet | Xu, Feng You, Wei Huang, Wei |
| author_sort | Xu, Feng |
| collection | PubMed |
| description | The title compound, [Cu(C(10)H(8)N(2))(3)]SO(4)·7.5H(2)O, is a six-coordinate copper(II) complex with a slightly elongated octahedral coordination geometry. The pyridyl rings of the three bipyridyl ligands are not coplanar, making dihedral angels of 9.5 (5), 5.2 (4) and 5.8 (5)°. In the crystal, several O—H⋯O and C—H⋯O hydrogen-bonding interactions are observed due to the existance of a large number of water molecules and the sulfate dianions. |
| format | Text |
| id | pubmed-2968254 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29682542010-12-30 Tris(2,2′-bipyridyl-κ(2) N,N′)copper(II) sulfate 7.5-hydrate Xu, Feng You, Wei Huang, Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(C(10)H(8)N(2))(3)]SO(4)·7.5H(2)O, is a six-coordinate copper(II) complex with a slightly elongated octahedral coordination geometry. The pyridyl rings of the three bipyridyl ligands are not coplanar, making dihedral angels of 9.5 (5), 5.2 (4) and 5.8 (5)°. In the crystal, several O—H⋯O and C—H⋯O hydrogen-bonding interactions are observed due to the existance of a large number of water molecules and the sulfate dianions. International Union of Crystallography 2009-01-08 /pmc/articles/PMC2968254/ /pubmed/21581747 http://dx.doi.org/10.1107/S1600536808043821 Text en © Xu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Xu, Feng You, Wei Huang, Wei Tris(2,2′-bipyridyl-κ(2) N,N′)copper(II) sulfate 7.5-hydrate |
| title | Tris(2,2′-bipyridyl-κ(2)
N,N′)copper(II) sulfate 7.5-hydrate |
| title_full | Tris(2,2′-bipyridyl-κ(2)
N,N′)copper(II) sulfate 7.5-hydrate |
| title_fullStr | Tris(2,2′-bipyridyl-κ(2)
N,N′)copper(II) sulfate 7.5-hydrate |
| title_full_unstemmed | Tris(2,2′-bipyridyl-κ(2)
N,N′)copper(II) sulfate 7.5-hydrate |
| title_short | Tris(2,2′-bipyridyl-κ(2)
N,N′)copper(II) sulfate 7.5-hydrate |
| title_sort | tris(2,2′-bipyridyl-κ(2)
n,n′)copper(ii) sulfate 7.5-hydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968254/ https://www.ncbi.nlm.nih.gov/pubmed/21581747 http://dx.doi.org/10.1107/S1600536808043821 |
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