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catena-Poly[[diaqua­calcium(II)]-di-μ-2-chloro­nicotinato]

The itle compound, [Ca(C(6)H(3)ClNO(2))(2)(H(2)O)(2)](n), contains polymeric chains extending along [100] that are generated by inversion centres. The Ca(2+) ions are bridged by 2-chloronicotinate groups and exhibit an eight-coordination by six carboxylate O atoms of four different 2-chloronicotinat...

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Detalles Bibliográficos
Autores principales: Quan, Li, Yin, Handong, Cui, Liansheng, Yang, Minglei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968257/
https://www.ncbi.nlm.nih.gov/pubmed/21581775
http://dx.doi.org/10.1107/S1600536808044267
Descripción
Sumario:The itle compound, [Ca(C(6)H(3)ClNO(2))(2)(H(2)O)(2)](n), contains polymeric chains extending along [100] that are generated by inversion centres. The Ca(2+) ions are bridged by 2-chloronicotinate groups and exhibit an eight-coordination by six carboxylate O atoms of four different 2-chloronicotinate ligands and two O atoms of water molecules. In the crystal structure, inter­molecular O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds result in the formation of a supra­molecular network structure. The π–π contacts between the 2-chloro­nicotinate rings [centroid–centroid distances = 3.875 (3) and 3.701 (3) Å] may further stabilize the structure.