Bis(6-meth­oxy-2-{[tris­(hydroxy­meth­yl)­meth­yl]­imino­meth­yl}phenolato)­copper(II) dihydrate

In the title compound, [Cu(C(12)H(16)NO(5))(2)]·2H(2)O, the Cu(II) ion adopts a trans-CuN(2)O(4) octa­hedral geometry arising from two N,O,O′-tridentate 6-meth­oxy-2-{[tris­(hydroxy­meth­yl)meth­yl]­imino­meth­yl}phenolate ligands. The Jahn–Teller distortion of the copper centre is unusally small. I...

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Detalles Bibliográficos
Autores principales: Zhang, Xiutang, Wei, Peihai, Dou, Jianmin, Li, Bin, Hu, Bo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968260/
https://www.ncbi.nlm.nih.gov/pubmed/21581764
http://dx.doi.org/10.1107/S1600536808043948
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author Zhang, Xiutang
Wei, Peihai
Dou, Jianmin
Li, Bin
Hu, Bo
author_facet Zhang, Xiutang
Wei, Peihai
Dou, Jianmin
Li, Bin
Hu, Bo
author_sort Zhang, Xiutang
collection PubMed
description In the title compound, [Cu(C(12)H(16)NO(5))(2)]·2H(2)O, the Cu(II) ion adopts a trans-CuN(2)O(4) octa­hedral geometry arising from two N,O,O′-tridentate 6-meth­oxy-2-{[tris­(hydroxy­meth­yl)meth­yl]­imino­meth­yl}phenolate ligands. The Jahn–Teller distortion of the copper centre is unusally small. In the crystal structure, O—H⋯O hydrogen bonds, some of which are bifurcated, link the component species.
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spelling pubmed-29682602010-12-30 Bis(6-meth­oxy-2-{[tris­(hydroxy­meth­yl)­meth­yl]­imino­meth­yl}phenolato)­copper(II) dihydrate Zhang, Xiutang Wei, Peihai Dou, Jianmin Li, Bin Hu, Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(12)H(16)NO(5))(2)]·2H(2)O, the Cu(II) ion adopts a trans-CuN(2)O(4) octa­hedral geometry arising from two N,O,O′-tridentate 6-meth­oxy-2-{[tris­(hydroxy­meth­yl)meth­yl]­imino­meth­yl}phenolate ligands. The Jahn–Teller distortion of the copper centre is unusally small. In the crystal structure, O—H⋯O hydrogen bonds, some of which are bifurcated, link the component species. International Union of Crystallography 2009-01-08 /pmc/articles/PMC2968260/ /pubmed/21581764 http://dx.doi.org/10.1107/S1600536808043948 Text en © Zhang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Xiutang
Wei, Peihai
Dou, Jianmin
Li, Bin
Hu, Bo
Bis(6-meth­oxy-2-{[tris­(hydroxy­meth­yl)­meth­yl]­imino­meth­yl}phenolato)­copper(II) dihydrate
title Bis(6-meth­oxy-2-{[tris­(hydroxy­meth­yl)­meth­yl]­imino­meth­yl}phenolato)­copper(II) dihydrate
title_full Bis(6-meth­oxy-2-{[tris­(hydroxy­meth­yl)­meth­yl]­imino­meth­yl}phenolato)­copper(II) dihydrate
title_fullStr Bis(6-meth­oxy-2-{[tris­(hydroxy­meth­yl)­meth­yl]­imino­meth­yl}phenolato)­copper(II) dihydrate
title_full_unstemmed Bis(6-meth­oxy-2-{[tris­(hydroxy­meth­yl)­meth­yl]­imino­meth­yl}phenolato)­copper(II) dihydrate
title_short Bis(6-meth­oxy-2-{[tris­(hydroxy­meth­yl)­meth­yl]­imino­meth­yl}phenolato)­copper(II) dihydrate
title_sort bis(6-meth­oxy-2-{[tris­(hydroxy­meth­yl)­meth­yl]­imino­meth­yl}phenolato)­copper(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968260/
https://www.ncbi.nlm.nih.gov/pubmed/21581764
http://dx.doi.org/10.1107/S1600536808043948
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AT doujianmin bis6methoxy2trishydroxymethylmethyliminomethylphenolatocopperiidihydrate
AT libin bis6methoxy2trishydroxymethylmethyliminomethylphenolatocopperiidihydrate
AT hubo bis6methoxy2trishydroxymethylmethyliminomethylphenolatocopperiidihydrate

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