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2,2′-(1-Phenyl-1H-pyrazole-3,5-diyl)diphenol
The title compound, C(21)H(16)N(2)O(2), was derived from 1-(2-hydroxyphenyl)-3-(-methoxyphenyl)propane-1,3-dione. The molecular structure of the title compound is stabilized by an intramolecular O—H⋯N hydrogen bond. The dihedral angle between the hydroxyphenyl ring involved in this intramole...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968261/ https://www.ncbi.nlm.nih.gov/pubmed/21581962 http://dx.doi.org/10.1107/S1600536809001226 |
Sumario: | The title compound, C(21)H(16)N(2)O(2), was derived from 1-(2-hydroxyphenyl)-3-(-methoxyphenyl)propane-1,3-dione. The molecular structure of the title compound is stabilized by an intramolecular O—H⋯N hydrogen bond. The dihedral angle between the hydroxyphenyl ring involved in this intramolecular hydrogen bond and the pyrazole ring is significantly smaller [10.07 (6)°] than the dihedral angle between the pyrazole and the other hydroxyphenyl ring [36.64 (5)°]. The benzene ring makes a dihedral angle of 54.95 (3)° with the pyrazole ring. The crystal packing is stabilized by O—H⋯O and O—H⋯N hydrogen bonds. |
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