2,2′-(1-Phenyl-1H-pyrazole-3,5-di­yl)diphenol

The title compound, C(21)H(16)N(2)O(2), was derived from 1-(2-hydroxy­phen­yl)-3-(-methoxy­phen­yl)propane-1,3-dione. The mol­ecular structure of the title compound is stabilized by an intra­molecular O—H⋯N hydrogen bond. The dihedral angle between the hydroxy­phenyl ring involved in this intra­mole...

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Detalles Bibliográficos
Autores principales: Ikram, Sumeera, Zia ul Haq, Muhammad, Badshah, Amir, Hasan, Aurangzeb, Bolte, Michael
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968261/
https://www.ncbi.nlm.nih.gov/pubmed/21581962
http://dx.doi.org/10.1107/S1600536809001226
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author Ikram, Sumeera
Zia ul Haq, Muhammad
Badshah, Amir
Hasan, Aurangzeb
Bolte, Michael
author_facet Ikram, Sumeera
Zia ul Haq, Muhammad
Badshah, Amir
Hasan, Aurangzeb
Bolte, Michael
author_sort Ikram, Sumeera
collection PubMed
description The title compound, C(21)H(16)N(2)O(2), was derived from 1-(2-hydroxy­phen­yl)-3-(-methoxy­phen­yl)propane-1,3-dione. The mol­ecular structure of the title compound is stabilized by an intra­molecular O—H⋯N hydrogen bond. The dihedral angle between the hydroxy­phenyl ring involved in this intra­molecular hydrogen bond and the pyrazole ring is significantly smaller [10.07 (6)°] than the dihedral angle between the pyrazole and the other hydroxy­phenyl ring [36.64 (5)°]. The benzene ring makes a dihedral angle of 54.95 (3)° with the pyrazole ring. The crystal packing is stabilized by O—H⋯O and O—H⋯N hydrogen bonds.
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spelling pubmed-29682612010-12-30 2,2′-(1-Phenyl-1H-pyrazole-3,5-di­yl)diphenol Ikram, Sumeera Zia ul Haq, Muhammad Badshah, Amir Hasan, Aurangzeb Bolte, Michael Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(21)H(16)N(2)O(2), was derived from 1-(2-hydroxy­phen­yl)-3-(-methoxy­phen­yl)propane-1,3-dione. The mol­ecular structure of the title compound is stabilized by an intra­molecular O—H⋯N hydrogen bond. The dihedral angle between the hydroxy­phenyl ring involved in this intra­molecular hydrogen bond and the pyrazole ring is significantly smaller [10.07 (6)°] than the dihedral angle between the pyrazole and the other hydroxy­phenyl ring [36.64 (5)°]. The benzene ring makes a dihedral angle of 54.95 (3)° with the pyrazole ring. The crystal packing is stabilized by O—H⋯O and O—H⋯N hydrogen bonds. International Union of Crystallography 2009-01-23 /pmc/articles/PMC2968261/ /pubmed/21581962 http://dx.doi.org/10.1107/S1600536809001226 Text en © Ikram et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ikram, Sumeera
Zia ul Haq, Muhammad
Badshah, Amir
Hasan, Aurangzeb
Bolte, Michael
2,2′-(1-Phenyl-1H-pyrazole-3,5-di­yl)diphenol
title 2,2′-(1-Phenyl-1H-pyrazole-3,5-di­yl)diphenol
title_full 2,2′-(1-Phenyl-1H-pyrazole-3,5-di­yl)diphenol
title_fullStr 2,2′-(1-Phenyl-1H-pyrazole-3,5-di­yl)diphenol
title_full_unstemmed 2,2′-(1-Phenyl-1H-pyrazole-3,5-di­yl)diphenol
title_short 2,2′-(1-Phenyl-1H-pyrazole-3,5-di­yl)diphenol
title_sort 2,2′-(1-phenyl-1h-pyrazole-3,5-di­yl)diphenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968261/
https://www.ncbi.nlm.nih.gov/pubmed/21581962
http://dx.doi.org/10.1107/S1600536809001226
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AT hasanaurangzeb 221phenyl1hpyrazole35diyldiphenol
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