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2-(2-Fur­yl)-1H-imidazo[4,5-f][1,10]phenanthroline-3,7-diium dichloride monohydrate

The organic cation of the title salt, C(17)H(12)N(4)O(2+)·2Cl(−)·H(2)O, is nearly planar, the dihedral angle between two pyridine rings being 2.53 (16)° and that between the pyridinum and furan rings being 4.17 (19)°. Mol­ecules are linked via N—H⋯O, N—H⋯Cl and O—H⋯Cl hydrogen bonds, forming a three...

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Autores principales: Chen, Ming-Hua, Zhang, Yun-Qian, Zhu, Qian-Jiang, Xue, Sai-Feng, Tao, Zhu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968264/
https://www.ncbi.nlm.nih.gov/pubmed/21581942
http://dx.doi.org/10.1107/S1600536809001160
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author Chen, Ming-Hua
Zhang, Yun-Qian
Zhu, Qian-Jiang
Xue, Sai-Feng
Tao, Zhu
author_facet Chen, Ming-Hua
Zhang, Yun-Qian
Zhu, Qian-Jiang
Xue, Sai-Feng
Tao, Zhu
author_sort Chen, Ming-Hua
collection PubMed
description The organic cation of the title salt, C(17)H(12)N(4)O(2+)·2Cl(−)·H(2)O, is nearly planar, the dihedral angle between two pyridine rings being 2.53 (16)° and that between the pyridinum and furan rings being 4.17 (19)°. Mol­ecules are linked via N—H⋯O, N—H⋯Cl and O—H⋯Cl hydrogen bonds, forming a three-dimensional framework and π–π stacking inter­actions help to stabilize the crystal structure [the imidazole–pyridine and imidazole–benzene centroid–centroid distances are 3.501 (3) and 3.674 (3) Å; respectively].
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spelling pubmed-29682642010-12-30 2-(2-Fur­yl)-1H-imidazo[4,5-f][1,10]phenanthroline-3,7-diium dichloride monohydrate Chen, Ming-Hua Zhang, Yun-Qian Zhu, Qian-Jiang Xue, Sai-Feng Tao, Zhu Acta Crystallogr Sect E Struct Rep Online Organic Papers The organic cation of the title salt, C(17)H(12)N(4)O(2+)·2Cl(−)·H(2)O, is nearly planar, the dihedral angle between two pyridine rings being 2.53 (16)° and that between the pyridinum and furan rings being 4.17 (19)°. Mol­ecules are linked via N—H⋯O, N—H⋯Cl and O—H⋯Cl hydrogen bonds, forming a three-dimensional framework and π–π stacking inter­actions help to stabilize the crystal structure [the imidazole–pyridine and imidazole–benzene centroid–centroid distances are 3.501 (3) and 3.674 (3) Å; respectively]. International Union of Crystallography 2009-01-17 /pmc/articles/PMC2968264/ /pubmed/21581942 http://dx.doi.org/10.1107/S1600536809001160 Text en © Chen et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chen, Ming-Hua
Zhang, Yun-Qian
Zhu, Qian-Jiang
Xue, Sai-Feng
Tao, Zhu
2-(2-Fur­yl)-1H-imidazo[4,5-f][1,10]phenanthroline-3,7-diium dichloride monohydrate
title 2-(2-Fur­yl)-1H-imidazo[4,5-f][1,10]phenanthroline-3,7-diium dichloride monohydrate
title_full 2-(2-Fur­yl)-1H-imidazo[4,5-f][1,10]phenanthroline-3,7-diium dichloride monohydrate
title_fullStr 2-(2-Fur­yl)-1H-imidazo[4,5-f][1,10]phenanthroline-3,7-diium dichloride monohydrate
title_full_unstemmed 2-(2-Fur­yl)-1H-imidazo[4,5-f][1,10]phenanthroline-3,7-diium dichloride monohydrate
title_short 2-(2-Fur­yl)-1H-imidazo[4,5-f][1,10]phenanthroline-3,7-diium dichloride monohydrate
title_sort 2-(2-fur­yl)-1h-imidazo[4,5-f][1,10]phenanthroline-3,7-diium dichloride monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968264/
https://www.ncbi.nlm.nih.gov/pubmed/21581942
http://dx.doi.org/10.1107/S1600536809001160
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