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2-(2-Furyl)-1H-imidazo[4,5-f][1,10]phenanthroline-3,7-diium dichloride monohydrate
The organic cation of the title salt, C(17)H(12)N(4)O(2+)·2Cl(−)·H(2)O, is nearly planar, the dihedral angle between two pyridine rings being 2.53 (16)° and that between the pyridinum and furan rings being 4.17 (19)°. Molecules are linked via N—H⋯O, N—H⋯Cl and O—H⋯Cl hydrogen bonds, forming a three...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968264/ https://www.ncbi.nlm.nih.gov/pubmed/21581942 http://dx.doi.org/10.1107/S1600536809001160 |
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author | Chen, Ming-Hua Zhang, Yun-Qian Zhu, Qian-Jiang Xue, Sai-Feng Tao, Zhu |
author_facet | Chen, Ming-Hua Zhang, Yun-Qian Zhu, Qian-Jiang Xue, Sai-Feng Tao, Zhu |
author_sort | Chen, Ming-Hua |
collection | PubMed |
description | The organic cation of the title salt, C(17)H(12)N(4)O(2+)·2Cl(−)·H(2)O, is nearly planar, the dihedral angle between two pyridine rings being 2.53 (16)° and that between the pyridinum and furan rings being 4.17 (19)°. Molecules are linked via N—H⋯O, N—H⋯Cl and O—H⋯Cl hydrogen bonds, forming a three-dimensional framework and π–π stacking interactions help to stabilize the crystal structure [the imidazole–pyridine and imidazole–benzene centroid–centroid distances are 3.501 (3) and 3.674 (3) Å; respectively]. |
format | Text |
id | pubmed-2968264 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29682642010-12-30 2-(2-Furyl)-1H-imidazo[4,5-f][1,10]phenanthroline-3,7-diium dichloride monohydrate Chen, Ming-Hua Zhang, Yun-Qian Zhu, Qian-Jiang Xue, Sai-Feng Tao, Zhu Acta Crystallogr Sect E Struct Rep Online Organic Papers The organic cation of the title salt, C(17)H(12)N(4)O(2+)·2Cl(−)·H(2)O, is nearly planar, the dihedral angle between two pyridine rings being 2.53 (16)° and that between the pyridinum and furan rings being 4.17 (19)°. Molecules are linked via N—H⋯O, N—H⋯Cl and O—H⋯Cl hydrogen bonds, forming a three-dimensional framework and π–π stacking interactions help to stabilize the crystal structure [the imidazole–pyridine and imidazole–benzene centroid–centroid distances are 3.501 (3) and 3.674 (3) Å; respectively]. International Union of Crystallography 2009-01-17 /pmc/articles/PMC2968264/ /pubmed/21581942 http://dx.doi.org/10.1107/S1600536809001160 Text en © Chen et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Chen, Ming-Hua Zhang, Yun-Qian Zhu, Qian-Jiang Xue, Sai-Feng Tao, Zhu 2-(2-Furyl)-1H-imidazo[4,5-f][1,10]phenanthroline-3,7-diium dichloride monohydrate |
title | 2-(2-Furyl)-1H-imidazo[4,5-f][1,10]phenanthroline-3,7-diium dichloride monohydrate |
title_full | 2-(2-Furyl)-1H-imidazo[4,5-f][1,10]phenanthroline-3,7-diium dichloride monohydrate |
title_fullStr | 2-(2-Furyl)-1H-imidazo[4,5-f][1,10]phenanthroline-3,7-diium dichloride monohydrate |
title_full_unstemmed | 2-(2-Furyl)-1H-imidazo[4,5-f][1,10]phenanthroline-3,7-diium dichloride monohydrate |
title_short | 2-(2-Furyl)-1H-imidazo[4,5-f][1,10]phenanthroline-3,7-diium dichloride monohydrate |
title_sort | 2-(2-furyl)-1h-imidazo[4,5-f][1,10]phenanthroline-3,7-diium dichloride monohydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968264/ https://www.ncbi.nlm.nih.gov/pubmed/21581942 http://dx.doi.org/10.1107/S1600536809001160 |
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