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Bis(4-ammonio-4-methyl­pentan-2-one-κO)dioxalato-κ(4) O (1),O (2)-copper(II)

The title compound, [Cu(C(2)O(4))(2)(C(6)H(14)NO)(2)], was synthesized by mixing diacetonamine hydrogen oxalate and copper sulfate in ethanol/water. The mol­ecule is centrosymmetric, so two pairs of equivalent ligands lie trans to each other. The Cu(II) center, located on a position with 2/m site sy...

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Detalles Bibliográficos
Autores principales: Ji, Zhiqin, Wei, Shaopeng, Wu, Wenjun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968265/
https://www.ncbi.nlm.nih.gov/pubmed/21581786
http://dx.doi.org/10.1107/S1600536808042396
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author Ji, Zhiqin
Wei, Shaopeng
Wu, Wenjun
author_facet Ji, Zhiqin
Wei, Shaopeng
Wu, Wenjun
author_sort Ji, Zhiqin
collection PubMed
description The title compound, [Cu(C(2)O(4))(2)(C(6)H(14)NO)(2)], was synthesized by mixing diacetonamine hydrogen oxalate and copper sulfate in ethanol/water. The mol­ecule is centrosymmetric, so two pairs of equivalent ligands lie trans to each other. The Cu(II) center, located on a position with 2/m site symmetry, is six-coordinated by four O atoms from two oxalate ligands at short distances and the carbonyl O atoms from the 4-amino-4-methyl­pentan-2-one ligands at longer distances. Mol­ecules are linked through inter­molecular N—H⋯O hydrogen bonds between the amino groups and carbonyl O atoms; no intra­molecular hydrogen bonds are formed.
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spelling pubmed-29682652010-12-30 Bis(4-ammonio-4-methyl­pentan-2-one-κO)dioxalato-κ(4) O (1),O (2)-copper(II) Ji, Zhiqin Wei, Shaopeng Wu, Wenjun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(C(2)O(4))(2)(C(6)H(14)NO)(2)], was synthesized by mixing diacetonamine hydrogen oxalate and copper sulfate in ethanol/water. The mol­ecule is centrosymmetric, so two pairs of equivalent ligands lie trans to each other. The Cu(II) center, located on a position with 2/m site symmetry, is six-coordinated by four O atoms from two oxalate ligands at short distances and the carbonyl O atoms from the 4-amino-4-methyl­pentan-2-one ligands at longer distances. Mol­ecules are linked through inter­molecular N—H⋯O hydrogen bonds between the amino groups and carbonyl O atoms; no intra­molecular hydrogen bonds are formed. International Union of Crystallography 2009-01-14 /pmc/articles/PMC2968265/ /pubmed/21581786 http://dx.doi.org/10.1107/S1600536808042396 Text en © Ji et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ji, Zhiqin
Wei, Shaopeng
Wu, Wenjun
Bis(4-ammonio-4-methyl­pentan-2-one-κO)dioxalato-κ(4) O (1),O (2)-copper(II)
title Bis(4-ammonio-4-methyl­pentan-2-one-κO)dioxalato-κ(4) O (1),O (2)-copper(II)
title_full Bis(4-ammonio-4-methyl­pentan-2-one-κO)dioxalato-κ(4) O (1),O (2)-copper(II)
title_fullStr Bis(4-ammonio-4-methyl­pentan-2-one-κO)dioxalato-κ(4) O (1),O (2)-copper(II)
title_full_unstemmed Bis(4-ammonio-4-methyl­pentan-2-one-κO)dioxalato-κ(4) O (1),O (2)-copper(II)
title_short Bis(4-ammonio-4-methyl­pentan-2-one-κO)dioxalato-κ(4) O (1),O (2)-copper(II)
title_sort bis(4-ammonio-4-methyl­pentan-2-one-κo)dioxalato-κ(4) o (1),o (2)-copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968265/
https://www.ncbi.nlm.nih.gov/pubmed/21581786
http://dx.doi.org/10.1107/S1600536808042396
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