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Bis(4-ammonio-4-methylpentan-2-one-κO)dioxalato-κ(4) O (1),O (2)-copper(II)
The title compound, [Cu(C(2)O(4))(2)(C(6)H(14)NO)(2)], was synthesized by mixing diacetonamine hydrogen oxalate and copper sulfate in ethanol/water. The molecule is centrosymmetric, so two pairs of equivalent ligands lie trans to each other. The Cu(II) center, located on a position with 2/m site sy...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968265/ https://www.ncbi.nlm.nih.gov/pubmed/21581786 http://dx.doi.org/10.1107/S1600536808042396 |
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author | Ji, Zhiqin Wei, Shaopeng Wu, Wenjun |
author_facet | Ji, Zhiqin Wei, Shaopeng Wu, Wenjun |
author_sort | Ji, Zhiqin |
collection | PubMed |
description | The title compound, [Cu(C(2)O(4))(2)(C(6)H(14)NO)(2)], was synthesized by mixing diacetonamine hydrogen oxalate and copper sulfate in ethanol/water. The molecule is centrosymmetric, so two pairs of equivalent ligands lie trans to each other. The Cu(II) center, located on a position with 2/m site symmetry, is six-coordinated by four O atoms from two oxalate ligands at short distances and the carbonyl O atoms from the 4-amino-4-methylpentan-2-one ligands at longer distances. Molecules are linked through intermolecular N—H⋯O hydrogen bonds between the amino groups and carbonyl O atoms; no intramolecular hydrogen bonds are formed. |
format | Text |
id | pubmed-2968265 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29682652010-12-30 Bis(4-ammonio-4-methylpentan-2-one-κO)dioxalato-κ(4) O (1),O (2)-copper(II) Ji, Zhiqin Wei, Shaopeng Wu, Wenjun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(C(2)O(4))(2)(C(6)H(14)NO)(2)], was synthesized by mixing diacetonamine hydrogen oxalate and copper sulfate in ethanol/water. The molecule is centrosymmetric, so two pairs of equivalent ligands lie trans to each other. The Cu(II) center, located on a position with 2/m site symmetry, is six-coordinated by four O atoms from two oxalate ligands at short distances and the carbonyl O atoms from the 4-amino-4-methylpentan-2-one ligands at longer distances. Molecules are linked through intermolecular N—H⋯O hydrogen bonds between the amino groups and carbonyl O atoms; no intramolecular hydrogen bonds are formed. International Union of Crystallography 2009-01-14 /pmc/articles/PMC2968265/ /pubmed/21581786 http://dx.doi.org/10.1107/S1600536808042396 Text en © Ji et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ji, Zhiqin Wei, Shaopeng Wu, Wenjun Bis(4-ammonio-4-methylpentan-2-one-κO)dioxalato-κ(4) O (1),O (2)-copper(II) |
title | Bis(4-ammonio-4-methylpentan-2-one-κO)dioxalato-κ(4)
O
(1),O
(2)-copper(II) |
title_full | Bis(4-ammonio-4-methylpentan-2-one-κO)dioxalato-κ(4)
O
(1),O
(2)-copper(II) |
title_fullStr | Bis(4-ammonio-4-methylpentan-2-one-κO)dioxalato-κ(4)
O
(1),O
(2)-copper(II) |
title_full_unstemmed | Bis(4-ammonio-4-methylpentan-2-one-κO)dioxalato-κ(4)
O
(1),O
(2)-copper(II) |
title_short | Bis(4-ammonio-4-methylpentan-2-one-κO)dioxalato-κ(4)
O
(1),O
(2)-copper(II) |
title_sort | bis(4-ammonio-4-methylpentan-2-one-κo)dioxalato-κ(4)
o
(1),o
(2)-copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968265/ https://www.ncbi.nlm.nih.gov/pubmed/21581786 http://dx.doi.org/10.1107/S1600536808042396 |
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