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3-Chloro-N-(diphenyl­carbamothio­yl)benzamide

In the title compound, C(20)H(15)ClN(2)OS, the bond lengths and angles in the thio­urea group are typical of thio­urea derivatives. The C—N bond lengths in the center of the mol­ecule are shorter than the normal C—N single bond due to the resonance effects in this part of the mol­ecule. The conforma...

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Detalles Bibliográficos
Autores principales: Binzet, Gün, Flörke, Ulrich, Külcü, Nevzat, Arslan, Hakan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968266/
https://www.ncbi.nlm.nih.gov/pubmed/21581951
http://dx.doi.org/10.1107/S1600536809001639
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author Binzet, Gün
Flörke, Ulrich
Külcü, Nevzat
Arslan, Hakan
author_facet Binzet, Gün
Flörke, Ulrich
Külcü, Nevzat
Arslan, Hakan
author_sort Binzet, Gün
collection PubMed
description In the title compound, C(20)H(15)ClN(2)OS, the bond lengths and angles in the thio­urea group are typical of thio­urea derivatives. The C—N bond lengths in the center of the mol­ecule are shorter than the normal C—N single bond due to the resonance effects in this part of the mol­ecule. The conformation of the title mol­ecule with respect to the thio­carbonyl and carbonyl groups is twisted, as reflected by the C—N—C—O and C—N—C—N torsion angles of −4.4 (6) and −53.3 (5)°, respectively. Pairs of the mol­ecules are linked into centrosymmetric dimers, stacked along the c axis via inter­molecular N—H⋯S inter­actions. There are also weak inter­molecular C—H⋯O and C—H⋯S contacts in the structure.
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spelling pubmed-29682662010-12-30 3-Chloro-N-(diphenyl­carbamothio­yl)benzamide Binzet, Gün Flörke, Ulrich Külcü, Nevzat Arslan, Hakan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(15)ClN(2)OS, the bond lengths and angles in the thio­urea group are typical of thio­urea derivatives. The C—N bond lengths in the center of the mol­ecule are shorter than the normal C—N single bond due to the resonance effects in this part of the mol­ecule. The conformation of the title mol­ecule with respect to the thio­carbonyl and carbonyl groups is twisted, as reflected by the C—N—C—O and C—N—C—N torsion angles of −4.4 (6) and −53.3 (5)°, respectively. Pairs of the mol­ecules are linked into centrosymmetric dimers, stacked along the c axis via inter­molecular N—H⋯S inter­actions. There are also weak inter­molecular C—H⋯O and C—H⋯S contacts in the structure. International Union of Crystallography 2009-01-17 /pmc/articles/PMC2968266/ /pubmed/21581951 http://dx.doi.org/10.1107/S1600536809001639 Text en © Binzet et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Binzet, Gün
Flörke, Ulrich
Külcü, Nevzat
Arslan, Hakan
3-Chloro-N-(diphenyl­carbamothio­yl)benzamide
title 3-Chloro-N-(diphenyl­carbamothio­yl)benzamide
title_full 3-Chloro-N-(diphenyl­carbamothio­yl)benzamide
title_fullStr 3-Chloro-N-(diphenyl­carbamothio­yl)benzamide
title_full_unstemmed 3-Chloro-N-(diphenyl­carbamothio­yl)benzamide
title_short 3-Chloro-N-(diphenyl­carbamothio­yl)benzamide
title_sort 3-chloro-n-(diphenyl­carbamothio­yl)benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968266/
https://www.ncbi.nlm.nih.gov/pubmed/21581951
http://dx.doi.org/10.1107/S1600536809001639
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