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3-Chloro-N-(diphenylcarbamothioyl)benzamide
In the title compound, C(20)H(15)ClN(2)OS, the bond lengths and angles in the thiourea group are typical of thiourea derivatives. The C—N bond lengths in the center of the molecule are shorter than the normal C—N single bond due to the resonance effects in this part of the molecule. The conforma...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968266/ https://www.ncbi.nlm.nih.gov/pubmed/21581951 http://dx.doi.org/10.1107/S1600536809001639 |
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author | Binzet, Gün Flörke, Ulrich Külcü, Nevzat Arslan, Hakan |
author_facet | Binzet, Gün Flörke, Ulrich Külcü, Nevzat Arslan, Hakan |
author_sort | Binzet, Gün |
collection | PubMed |
description | In the title compound, C(20)H(15)ClN(2)OS, the bond lengths and angles in the thiourea group are typical of thiourea derivatives. The C—N bond lengths in the center of the molecule are shorter than the normal C—N single bond due to the resonance effects in this part of the molecule. The conformation of the title molecule with respect to the thiocarbonyl and carbonyl groups is twisted, as reflected by the C—N—C—O and C—N—C—N torsion angles of −4.4 (6) and −53.3 (5)°, respectively. Pairs of the molecules are linked into centrosymmetric dimers, stacked along the c axis via intermolecular N—H⋯S interactions. There are also weak intermolecular C—H⋯O and C—H⋯S contacts in the structure. |
format | Text |
id | pubmed-2968266 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29682662010-12-30 3-Chloro-N-(diphenylcarbamothioyl)benzamide Binzet, Gün Flörke, Ulrich Külcü, Nevzat Arslan, Hakan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(15)ClN(2)OS, the bond lengths and angles in the thiourea group are typical of thiourea derivatives. The C—N bond lengths in the center of the molecule are shorter than the normal C—N single bond due to the resonance effects in this part of the molecule. The conformation of the title molecule with respect to the thiocarbonyl and carbonyl groups is twisted, as reflected by the C—N—C—O and C—N—C—N torsion angles of −4.4 (6) and −53.3 (5)°, respectively. Pairs of the molecules are linked into centrosymmetric dimers, stacked along the c axis via intermolecular N—H⋯S interactions. There are also weak intermolecular C—H⋯O and C—H⋯S contacts in the structure. International Union of Crystallography 2009-01-17 /pmc/articles/PMC2968266/ /pubmed/21581951 http://dx.doi.org/10.1107/S1600536809001639 Text en © Binzet et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Binzet, Gün Flörke, Ulrich Külcü, Nevzat Arslan, Hakan 3-Chloro-N-(diphenylcarbamothioyl)benzamide |
title | 3-Chloro-N-(diphenylcarbamothioyl)benzamide |
title_full | 3-Chloro-N-(diphenylcarbamothioyl)benzamide |
title_fullStr | 3-Chloro-N-(diphenylcarbamothioyl)benzamide |
title_full_unstemmed | 3-Chloro-N-(diphenylcarbamothioyl)benzamide |
title_short | 3-Chloro-N-(diphenylcarbamothioyl)benzamide |
title_sort | 3-chloro-n-(diphenylcarbamothioyl)benzamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968266/ https://www.ncbi.nlm.nih.gov/pubmed/21581951 http://dx.doi.org/10.1107/S1600536809001639 |
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