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Bis(2,2′-bipyridine-κ(2) N,N′)dichlorido­platinum(IV) dichloride monohydrate

In the title complex, [PtCl(2)(C(10)H(8)N(2))(2)]Cl(2)·H(2)O, the Pt(4+) ion is six-coordinated in a distorted octa­hedral environment by four N atoms from the two 2,2′-bipyridine ligands and two Cl atoms. As a result of the different trans influences of the N and Cl atoms, the Pt—N bonds trans to t...

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Detalles Bibliográficos
Autores principales: Kim, Nam-Ho, Hwang, In-Chul, Ha, Kwang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968269/
https://www.ncbi.nlm.nih.gov/pubmed/21581784
http://dx.doi.org/10.1107/S1600536809000725
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author Kim, Nam-Ho
Hwang, In-Chul
Ha, Kwang
author_facet Kim, Nam-Ho
Hwang, In-Chul
Ha, Kwang
author_sort Kim, Nam-Ho
collection PubMed
description In the title complex, [PtCl(2)(C(10)H(8)N(2))(2)]Cl(2)·H(2)O, the Pt(4+) ion is six-coordinated in a distorted octa­hedral environment by four N atoms from the two 2,2′-bipyridine ligands and two Cl atoms. As a result of the different trans influences of the N and Cl atoms, the Pt—N bonds trans to the Cl atom are slightly longer than those trans to the N atom. The compound displays inter­molecular hydrogen bonding between the water mol­ecule and the Cl anions. There are inter­molecular π–π inter­actions between adjacent pyridine rings, with a centroid–centroid distance of 3.962 Å.
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spelling pubmed-29682692010-12-30 Bis(2,2′-bipyridine-κ(2) N,N′)dichlorido­platinum(IV) dichloride monohydrate Kim, Nam-Ho Hwang, In-Chul Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [PtCl(2)(C(10)H(8)N(2))(2)]Cl(2)·H(2)O, the Pt(4+) ion is six-coordinated in a distorted octa­hedral environment by four N atoms from the two 2,2′-bipyridine ligands and two Cl atoms. As a result of the different trans influences of the N and Cl atoms, the Pt—N bonds trans to the Cl atom are slightly longer than those trans to the N atom. The compound displays inter­molecular hydrogen bonding between the water mol­ecule and the Cl anions. There are inter­molecular π–π inter­actions between adjacent pyridine rings, with a centroid–centroid distance of 3.962 Å. International Union of Crystallography 2009-01-14 /pmc/articles/PMC2968269/ /pubmed/21581784 http://dx.doi.org/10.1107/S1600536809000725 Text en © Kim et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kim, Nam-Ho
Hwang, In-Chul
Ha, Kwang
Bis(2,2′-bipyridine-κ(2) N,N′)dichlorido­platinum(IV) dichloride monohydrate
title Bis(2,2′-bipyridine-κ(2) N,N′)dichlorido­platinum(IV) dichloride monohydrate
title_full Bis(2,2′-bipyridine-κ(2) N,N′)dichlorido­platinum(IV) dichloride monohydrate
title_fullStr Bis(2,2′-bipyridine-κ(2) N,N′)dichlorido­platinum(IV) dichloride monohydrate
title_full_unstemmed Bis(2,2′-bipyridine-κ(2) N,N′)dichlorido­platinum(IV) dichloride monohydrate
title_short Bis(2,2′-bipyridine-κ(2) N,N′)dichlorido­platinum(IV) dichloride monohydrate
title_sort bis(2,2′-bipyridine-κ(2) n,n′)dichlorido­platinum(iv) dichloride monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968269/
https://www.ncbi.nlm.nih.gov/pubmed/21581784
http://dx.doi.org/10.1107/S1600536809000725
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