Cargando…
Bis(2,2′-bipyridine-κ(2) N,N′)dichloridoplatinum(IV) dichloride monohydrate
In the title complex, [PtCl(2)(C(10)H(8)N(2))(2)]Cl(2)·H(2)O, the Pt(4+) ion is six-coordinated in a distorted octahedral environment by four N atoms from the two 2,2′-bipyridine ligands and two Cl atoms. As a result of the different trans influences of the N and Cl atoms, the Pt—N bonds trans to t...
Autores principales: | , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968269/ https://www.ncbi.nlm.nih.gov/pubmed/21581784 http://dx.doi.org/10.1107/S1600536809000725 |
_version_ | 1782189824307888128 |
---|---|
author | Kim, Nam-Ho Hwang, In-Chul Ha, Kwang |
author_facet | Kim, Nam-Ho Hwang, In-Chul Ha, Kwang |
author_sort | Kim, Nam-Ho |
collection | PubMed |
description | In the title complex, [PtCl(2)(C(10)H(8)N(2))(2)]Cl(2)·H(2)O, the Pt(4+) ion is six-coordinated in a distorted octahedral environment by four N atoms from the two 2,2′-bipyridine ligands and two Cl atoms. As a result of the different trans influences of the N and Cl atoms, the Pt—N bonds trans to the Cl atom are slightly longer than those trans to the N atom. The compound displays intermolecular hydrogen bonding between the water molecule and the Cl anions. There are intermolecular π–π interactions between adjacent pyridine rings, with a centroid–centroid distance of 3.962 Å. |
format | Text |
id | pubmed-2968269 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29682692010-12-30 Bis(2,2′-bipyridine-κ(2) N,N′)dichloridoplatinum(IV) dichloride monohydrate Kim, Nam-Ho Hwang, In-Chul Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [PtCl(2)(C(10)H(8)N(2))(2)]Cl(2)·H(2)O, the Pt(4+) ion is six-coordinated in a distorted octahedral environment by four N atoms from the two 2,2′-bipyridine ligands and two Cl atoms. As a result of the different trans influences of the N and Cl atoms, the Pt—N bonds trans to the Cl atom are slightly longer than those trans to the N atom. The compound displays intermolecular hydrogen bonding between the water molecule and the Cl anions. There are intermolecular π–π interactions between adjacent pyridine rings, with a centroid–centroid distance of 3.962 Å. International Union of Crystallography 2009-01-14 /pmc/articles/PMC2968269/ /pubmed/21581784 http://dx.doi.org/10.1107/S1600536809000725 Text en © Kim et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Kim, Nam-Ho Hwang, In-Chul Ha, Kwang Bis(2,2′-bipyridine-κ(2) N,N′)dichloridoplatinum(IV) dichloride monohydrate |
title | Bis(2,2′-bipyridine-κ(2)
N,N′)dichloridoplatinum(IV) dichloride monohydrate |
title_full | Bis(2,2′-bipyridine-κ(2)
N,N′)dichloridoplatinum(IV) dichloride monohydrate |
title_fullStr | Bis(2,2′-bipyridine-κ(2)
N,N′)dichloridoplatinum(IV) dichloride monohydrate |
title_full_unstemmed | Bis(2,2′-bipyridine-κ(2)
N,N′)dichloridoplatinum(IV) dichloride monohydrate |
title_short | Bis(2,2′-bipyridine-κ(2)
N,N′)dichloridoplatinum(IV) dichloride monohydrate |
title_sort | bis(2,2′-bipyridine-κ(2)
n,n′)dichloridoplatinum(iv) dichloride monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968269/ https://www.ncbi.nlm.nih.gov/pubmed/21581784 http://dx.doi.org/10.1107/S1600536809000725 |
work_keys_str_mv | AT kimnamho bis22bipyridinek2nndichloridoplatinumivdichloridemonohydrate AT hwanginchul bis22bipyridinek2nndichloridoplatinumivdichloridemonohydrate AT hakwang bis22bipyridinek2nndichloridoplatinumivdichloridemonohydrate |