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(4,4′-Di-tert-butyl-2,2′-bipyridine-κ(2) N,N′)bis(nitrato-κ(2) O,O′)copper(II)
In the crystal of the title compound, [Cu(NO(3))(2)(C(18)H(24)N(2))], the Cu(II) ion is coordinated by two N atoms of the bipyridine ligand and four O atoms from the two nitrate anions in a distorted octahedral fashion. The dihedral angle between the planes of the two pyridine rings is 11.52 (10)°....
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968272/ https://www.ncbi.nlm.nih.gov/pubmed/21581800 http://dx.doi.org/10.1107/S1600536809001457 |
| _version_ | 1782189825085931520 |
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| author | Xiao, Xin Rao, Zai-Ying Zhang, Yun-Qiang Xue, Sai-Feng Tao, Zhu |
| author_facet | Xiao, Xin Rao, Zai-Ying Zhang, Yun-Qiang Xue, Sai-Feng Tao, Zhu |
| author_sort | Xiao, Xin |
| collection | PubMed |
| description | In the crystal of the title compound, [Cu(NO(3))(2)(C(18)H(24)N(2))], the Cu(II) ion is coordinated by two N atoms of the bipyridine ligand and four O atoms from the two nitrate anions in a distorted octahedral fashion. The dihedral angle between the planes of the two pyridine rings is 11.52 (10)°. In the crystal structure, weak C—H⋯O interactions may help to establish the packing. |
| format | Text |
| id | pubmed-2968272 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29682722010-12-30 (4,4′-Di-tert-butyl-2,2′-bipyridine-κ(2) N,N′)bis(nitrato-κ(2) O,O′)copper(II) Xiao, Xin Rao, Zai-Ying Zhang, Yun-Qiang Xue, Sai-Feng Tao, Zhu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal of the title compound, [Cu(NO(3))(2)(C(18)H(24)N(2))], the Cu(II) ion is coordinated by two N atoms of the bipyridine ligand and four O atoms from the two nitrate anions in a distorted octahedral fashion. The dihedral angle between the planes of the two pyridine rings is 11.52 (10)°. In the crystal structure, weak C—H⋯O interactions may help to establish the packing. International Union of Crystallography 2009-01-17 /pmc/articles/PMC2968272/ /pubmed/21581800 http://dx.doi.org/10.1107/S1600536809001457 Text en © Xiao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Xiao, Xin Rao, Zai-Ying Zhang, Yun-Qiang Xue, Sai-Feng Tao, Zhu (4,4′-Di-tert-butyl-2,2′-bipyridine-κ(2) N,N′)bis(nitrato-κ(2) O,O′)copper(II) |
| title | (4,4′-Di-tert-butyl-2,2′-bipyridine-κ(2)
N,N′)bis(nitrato-κ(2)
O,O′)copper(II) |
| title_full | (4,4′-Di-tert-butyl-2,2′-bipyridine-κ(2)
N,N′)bis(nitrato-κ(2)
O,O′)copper(II) |
| title_fullStr | (4,4′-Di-tert-butyl-2,2′-bipyridine-κ(2)
N,N′)bis(nitrato-κ(2)
O,O′)copper(II) |
| title_full_unstemmed | (4,4′-Di-tert-butyl-2,2′-bipyridine-κ(2)
N,N′)bis(nitrato-κ(2)
O,O′)copper(II) |
| title_short | (4,4′-Di-tert-butyl-2,2′-bipyridine-κ(2)
N,N′)bis(nitrato-κ(2)
O,O′)copper(II) |
| title_sort | (4,4′-di-tert-butyl-2,2′-bipyridine-κ(2)
n,n′)bis(nitrato-κ(2)
o,o′)copper(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968272/ https://www.ncbi.nlm.nih.gov/pubmed/21581800 http://dx.doi.org/10.1107/S1600536809001457 |
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