(E)-2-[(2-Amino-4,5-dibromo­phen­yl)imino­meth­yl]-6-methoxy­phenol

The title compound, C(14)H(12)Br(2)N(2)O(2), was prepared from the condensation of 4,5-dibromo-1,2-phenyl­enediamine and 2-hydr­oxy-3-methoxy­benzaldehyde in methanol. The N=C double bond shows a trans conformation and the dihedral angle between the aromatic ring planes is 5.9 (4)°. In the crystal s...

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Detalles Bibliográficos
Autores principales: Li, Zhan-Xian, Yang, Hui, Yu, Ming, Shi, Qiu-Zhi, Yu, Ming-Ming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968274/
https://www.ncbi.nlm.nih.gov/pubmed/21581858
http://dx.doi.org/10.1107/S1600536808044164
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author Li, Zhan-Xian
Yang, Hui
Yu, Ming
Shi, Qiu-Zhi
Yu, Ming-Ming
author_facet Li, Zhan-Xian
Yang, Hui
Yu, Ming
Shi, Qiu-Zhi
Yu, Ming-Ming
author_sort Li, Zhan-Xian
collection PubMed
description The title compound, C(14)H(12)Br(2)N(2)O(2), was prepared from the condensation of 4,5-dibromo-1,2-phenyl­enediamine and 2-hydr­oxy-3-methoxy­benzaldehyde in methanol. The N=C double bond shows a trans conformation and the dihedral angle between the aromatic ring planes is 5.9 (4)°. In the crystal structure, there are intra­molecular O—H⋯N and N—H⋯N and inter­molecular N—H⋯O hydrogen bonds, the latter resulting in inversion dimers.
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spelling pubmed-29682742010-12-30 (E)-2-[(2-Amino-4,5-dibromo­phen­yl)imino­meth­yl]-6-methoxy­phenol Li, Zhan-Xian Yang, Hui Yu, Ming Shi, Qiu-Zhi Yu, Ming-Ming Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(12)Br(2)N(2)O(2), was prepared from the condensation of 4,5-dibromo-1,2-phenyl­enediamine and 2-hydr­oxy-3-methoxy­benzaldehyde in methanol. The N=C double bond shows a trans conformation and the dihedral angle between the aromatic ring planes is 5.9 (4)°. In the crystal structure, there are intra­molecular O—H⋯N and N—H⋯N and inter­molecular N—H⋯O hydrogen bonds, the latter resulting in inversion dimers. International Union of Crystallography 2009-01-08 /pmc/articles/PMC2968274/ /pubmed/21581858 http://dx.doi.org/10.1107/S1600536808044164 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Zhan-Xian
Yang, Hui
Yu, Ming
Shi, Qiu-Zhi
Yu, Ming-Ming
(E)-2-[(2-Amino-4,5-dibromo­phen­yl)imino­meth­yl]-6-methoxy­phenol
title (E)-2-[(2-Amino-4,5-dibromo­phen­yl)imino­meth­yl]-6-methoxy­phenol
title_full (E)-2-[(2-Amino-4,5-dibromo­phen­yl)imino­meth­yl]-6-methoxy­phenol
title_fullStr (E)-2-[(2-Amino-4,5-dibromo­phen­yl)imino­meth­yl]-6-methoxy­phenol
title_full_unstemmed (E)-2-[(2-Amino-4,5-dibromo­phen­yl)imino­meth­yl]-6-methoxy­phenol
title_short (E)-2-[(2-Amino-4,5-dibromo­phen­yl)imino­meth­yl]-6-methoxy­phenol
title_sort (e)-2-[(2-amino-4,5-dibromo­phen­yl)imino­meth­yl]-6-methoxy­phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968274/
https://www.ncbi.nlm.nih.gov/pubmed/21581858
http://dx.doi.org/10.1107/S1600536808044164
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