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Bis{benzyl N′-[(1H-indol-3-yl)methyl­ene]dithio­carbazato-κ(2) N′,S}copper(II) N,N-dimethyl­formamide disolvate

In the structure of [Cu(C(17)H(14)N(3)S(2))(2)]·2C(3)H(7)NO, the Cu atom (site symmetry [Image: see text]) is N,S-chelated by the two deprotonated Schiff-base anions that define a distorted square-planar geometry. An N—H⋯O hydrogen bond links the mononuclear complex to the DMF solvent mol­ecules....

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Detalles Bibliográficos
Autores principales: Khaledi, Hamid, Mohd Ali, Hapipah, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968278/
https://www.ncbi.nlm.nih.gov/pubmed/21581755
http://dx.doi.org/10.1107/S1600536808043808
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author Khaledi, Hamid
Mohd Ali, Hapipah
Ng, Seik Weng
author_facet Khaledi, Hamid
Mohd Ali, Hapipah
Ng, Seik Weng
author_sort Khaledi, Hamid
collection PubMed
description In the structure of [Cu(C(17)H(14)N(3)S(2))(2)]·2C(3)H(7)NO, the Cu atom (site symmetry [Image: see text]) is N,S-chelated by the two deprotonated Schiff-base anions that define a distorted square-planar geometry. An N—H⋯O hydrogen bond links the mononuclear complex to the DMF solvent mol­ecules.
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spelling pubmed-29682782010-12-30 Bis{benzyl N′-[(1H-indol-3-yl)methyl­ene]dithio­carbazato-κ(2) N′,S}copper(II) N,N-dimethyl­formamide disolvate Khaledi, Hamid Mohd Ali, Hapipah Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of [Cu(C(17)H(14)N(3)S(2))(2)]·2C(3)H(7)NO, the Cu atom (site symmetry [Image: see text]) is N,S-chelated by the two deprotonated Schiff-base anions that define a distorted square-planar geometry. An N—H⋯O hydrogen bond links the mononuclear complex to the DMF solvent mol­ecules. International Union of Crystallography 2009-01-08 /pmc/articles/PMC2968278/ /pubmed/21581755 http://dx.doi.org/10.1107/S1600536808043808 Text en © Khaledi et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Khaledi, Hamid
Mohd Ali, Hapipah
Ng, Seik Weng
Bis{benzyl N′-[(1H-indol-3-yl)methyl­ene]dithio­carbazato-κ(2) N′,S}copper(II) N,N-dimethyl­formamide disolvate
title Bis{benzyl N′-[(1H-indol-3-yl)methyl­ene]dithio­carbazato-κ(2) N′,S}copper(II) N,N-dimethyl­formamide disolvate
title_full Bis{benzyl N′-[(1H-indol-3-yl)methyl­ene]dithio­carbazato-κ(2) N′,S}copper(II) N,N-dimethyl­formamide disolvate
title_fullStr Bis{benzyl N′-[(1H-indol-3-yl)methyl­ene]dithio­carbazato-κ(2) N′,S}copper(II) N,N-dimethyl­formamide disolvate
title_full_unstemmed Bis{benzyl N′-[(1H-indol-3-yl)methyl­ene]dithio­carbazato-κ(2) N′,S}copper(II) N,N-dimethyl­formamide disolvate
title_short Bis{benzyl N′-[(1H-indol-3-yl)methyl­ene]dithio­carbazato-κ(2) N′,S}copper(II) N,N-dimethyl­formamide disolvate
title_sort bis{benzyl n′-[(1h-indol-3-yl)methyl­ene]dithio­carbazato-κ(2) n′,s}copper(ii) n,n-dimethyl­formamide disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968278/
https://www.ncbi.nlm.nih.gov/pubmed/21581755
http://dx.doi.org/10.1107/S1600536808043808
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