catena-Poly[[diaqua­copper(II)]-μ-7-oxa­bicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato]

In the crystal structure of the title compound, [Cu(C(8)H(8)O(5))(H(2)O)(2)](n), the Cu(II) cation is in a Jahn–Teller distorted six-coordination by two O atoms from water molecules, by the bridging O atom from the bicyclo moiety, by two carboxylate O atoms from two different carboxylate groups and...

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Detalles Bibliográficos
Autores principales: Wang, Yun-Yun, Hu, Rui-Ding, Wang, Yan-Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968279/
https://www.ncbi.nlm.nih.gov/pubmed/21581776
http://dx.doi.org/10.1107/S1600536809000270
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author Wang, Yun-Yun
Hu, Rui-Ding
Wang, Yan-Jun
author_facet Wang, Yun-Yun
Hu, Rui-Ding
Wang, Yan-Jun
author_sort Wang, Yun-Yun
collection PubMed
description In the crystal structure of the title compound, [Cu(C(8)H(8)O(5))(H(2)O)(2)](n), the Cu(II) cation is in a Jahn–Teller distorted six-coordination by two O atoms from water molecules, by the bridging O atom from the bicyclo moiety, by two carboxylate O atoms from two different carboxylate groups and by one carboxylate O atom from a symmetry-related bridging ligand.The polymeric structure is made up from double-strands propagating parallel to the c axis that are held together via inter­molecular O—H⋯O hydrogen bonds.
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spelling pubmed-29682792010-12-30 catena-Poly[[diaqua­copper(II)]-μ-7-oxa­bicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato] Wang, Yun-Yun Hu, Rui-Ding Wang, Yan-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Cu(C(8)H(8)O(5))(H(2)O)(2)](n), the Cu(II) cation is in a Jahn–Teller distorted six-coordination by two O atoms from water molecules, by the bridging O atom from the bicyclo moiety, by two carboxylate O atoms from two different carboxylate groups and by one carboxylate O atom from a symmetry-related bridging ligand.The polymeric structure is made up from double-strands propagating parallel to the c axis that are held together via inter­molecular O—H⋯O hydrogen bonds. International Union of Crystallography 2009-01-10 /pmc/articles/PMC2968279/ /pubmed/21581776 http://dx.doi.org/10.1107/S1600536809000270 Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Yun-Yun
Hu, Rui-Ding
Wang, Yan-Jun
catena-Poly[[diaqua­copper(II)]-μ-7-oxa­bicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato]
title catena-Poly[[diaqua­copper(II)]-μ-7-oxa­bicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato]
title_full catena-Poly[[diaqua­copper(II)]-μ-7-oxa­bicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato]
title_fullStr catena-Poly[[diaqua­copper(II)]-μ-7-oxa­bicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato]
title_full_unstemmed catena-Poly[[diaqua­copper(II)]-μ-7-oxa­bicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato]
title_short catena-Poly[[diaqua­copper(II)]-μ-7-oxa­bicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato]
title_sort catena-poly[[diaqua­copper(ii)]-μ-7-oxa­bicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968279/
https://www.ncbi.nlm.nih.gov/pubmed/21581776
http://dx.doi.org/10.1107/S1600536809000270
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