2-{1-[2-((2-Ammonio­ethyl){2-[1-(5-chloro-2-hydroxy­phen­yl)ethyl­idene­amino]eth­yl}amino)ethyl­iminio]eth­yl}-4-chloro­phenolate trifluoro­acetate

In the title ion-pair, C(22)H(29)Cl(2)N(4)O(2) (+)·C(2)F(3)O(2) (−), ammonium–carboxyl­ate N—H⋯O hydrogen bonds link two cations and two anions about a centre of inversion to generate a hydrogen-bonded tetramer. In the cation, one of the imino N atoms is protonated and donates a hydrogen bond to the...

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Detalles Bibliográficos
Autores principales: Lee, See Mun, Ali, Hapipah Mohd., Lo, Kong Mun, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968282/
https://www.ncbi.nlm.nih.gov/pubmed/21582002
http://dx.doi.org/10.1107/S1600536809002943
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author Lee, See Mun
Ali, Hapipah Mohd.
Lo, Kong Mun
Ng, Seik Weng
author_facet Lee, See Mun
Ali, Hapipah Mohd.
Lo, Kong Mun
Ng, Seik Weng
author_sort Lee, See Mun
collection PubMed
description In the title ion-pair, C(22)H(29)Cl(2)N(4)O(2) (+)·C(2)F(3)O(2) (−), ammonium–carboxyl­ate N—H⋯O hydrogen bonds link two cations and two anions about a centre of inversion to generate a hydrogen-bonded tetramer. In the cation, one of the imino N atoms is protonated and donates a hydrogen bond to the O atom of the adjacent chloro­phenyl ring. The other imino N atom acts as a hydrogen-bond acceptor from a phenolate O atom.
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spelling pubmed-29682822010-12-30 2-{1-[2-((2-Ammonio­ethyl){2-[1-(5-chloro-2-hydroxy­phen­yl)ethyl­idene­amino]eth­yl}amino)ethyl­iminio]eth­yl}-4-chloro­phenolate trifluoro­acetate Lee, See Mun Ali, Hapipah Mohd. Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title ion-pair, C(22)H(29)Cl(2)N(4)O(2) (+)·C(2)F(3)O(2) (−), ammonium–carboxyl­ate N—H⋯O hydrogen bonds link two cations and two anions about a centre of inversion to generate a hydrogen-bonded tetramer. In the cation, one of the imino N atoms is protonated and donates a hydrogen bond to the O atom of the adjacent chloro­phenyl ring. The other imino N atom acts as a hydrogen-bond acceptor from a phenolate O atom. International Union of Crystallography 2009-01-28 /pmc/articles/PMC2968282/ /pubmed/21582002 http://dx.doi.org/10.1107/S1600536809002943 Text en © Lee et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lee, See Mun
Ali, Hapipah Mohd.
Lo, Kong Mun
Ng, Seik Weng
2-{1-[2-((2-Ammonio­ethyl){2-[1-(5-chloro-2-hydroxy­phen­yl)ethyl­idene­amino]eth­yl}amino)ethyl­iminio]eth­yl}-4-chloro­phenolate trifluoro­acetate
title 2-{1-[2-((2-Ammonio­ethyl){2-[1-(5-chloro-2-hydroxy­phen­yl)ethyl­idene­amino]eth­yl}amino)ethyl­iminio]eth­yl}-4-chloro­phenolate trifluoro­acetate
title_full 2-{1-[2-((2-Ammonio­ethyl){2-[1-(5-chloro-2-hydroxy­phen­yl)ethyl­idene­amino]eth­yl}amino)ethyl­iminio]eth­yl}-4-chloro­phenolate trifluoro­acetate
title_fullStr 2-{1-[2-((2-Ammonio­ethyl){2-[1-(5-chloro-2-hydroxy­phen­yl)ethyl­idene­amino]eth­yl}amino)ethyl­iminio]eth­yl}-4-chloro­phenolate trifluoro­acetate
title_full_unstemmed 2-{1-[2-((2-Ammonio­ethyl){2-[1-(5-chloro-2-hydroxy­phen­yl)ethyl­idene­amino]eth­yl}amino)ethyl­iminio]eth­yl}-4-chloro­phenolate trifluoro­acetate
title_short 2-{1-[2-((2-Ammonio­ethyl){2-[1-(5-chloro-2-hydroxy­phen­yl)ethyl­idene­amino]eth­yl}amino)ethyl­iminio]eth­yl}-4-chloro­phenolate trifluoro­acetate
title_sort 2-{1-[2-((2-ammonio­ethyl){2-[1-(5-chloro-2-hydroxy­phen­yl)ethyl­idene­amino]eth­yl}amino)ethyl­iminio]eth­yl}-4-chloro­phenolate trifluoro­acetate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968282/
https://www.ncbi.nlm.nih.gov/pubmed/21582002
http://dx.doi.org/10.1107/S1600536809002943
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AT alihapipahmohd 2122ammonioethyl215chloro2hydroxyphenylethylideneaminoethylaminoethyliminioethyl4chlorophenolatetrifluoroacetate
AT lokongmun 2122ammonioethyl215chloro2hydroxyphenylethylideneaminoethylaminoethyliminioethyl4chlorophenolatetrifluoroacetate
AT ngseikweng 2122ammonioethyl215chloro2hydroxyphenylethylideneaminoethylaminoethyliminioethyl4chlorophenolatetrifluoroacetate

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