Poly[1-ethyl-3-methyl­imidazolium [tri-μ-chlorido-chromate(II)]]

The title compound, {(C(6)H(11)N(2))[CrCl(3)]}(n), was generated via mixing of the ionic liquid 1-ethyl-3-methyl­imidazolium chloride with CrCl(2) in ethanol. Crystals were obtained by a diffusion method. In the crystal structure, the anion forms one-dimensional chains of chloride-bridged Jahn–Telle...

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Detalles Bibliográficos
Autores principales: Danford, James J., Arif, Atta M., Berreau, Lisa M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968286/
https://www.ncbi.nlm.nih.gov/pubmed/21581818
http://dx.doi.org/10.1107/S1600536809002281
Descripción
Sumario:The title compound, {(C(6)H(11)N(2))[CrCl(3)]}(n), was generated via mixing of the ionic liquid 1-ethyl-3-methyl­imidazolium chloride with CrCl(2) in ethanol. Crystals were obtained by a diffusion method. In the crystal structure, the anion forms one-dimensional chains of chloride-bridged Jahn–Teller distorted chromium(II) centers extending along the [100] direction. The imidazolium cations are positioned between these chains.

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