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[1,1′-Diphenyl-3,3′-(propane-1,3-diyldinitrilo)dibut-1-enolato]copper(II)
The title compound, [Cu(C(23)H(24)N(2)O(2))] or [Cu{(BA)(2)pn}], where (BA)(2)pn is 1,1′-diphenyl-3,3′-(propane-1,3-diyldinitrilo)dibut-1-enolate, is a mononuclear copper(II) complex, located on a twofold axis. The four-coordinate Cu(II) atom is in a tetrahedrally distorted square plane defined by...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968291/ https://www.ncbi.nlm.nih.gov/pubmed/21581795 http://dx.doi.org/10.1107/S1600536809001081 |
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author | Salehi, Mehdi Meghdadi, Soraia Amirnasr, Mehdi Mereiter, Kurt |
author_facet | Salehi, Mehdi Meghdadi, Soraia Amirnasr, Mehdi Mereiter, Kurt |
author_sort | Salehi, Mehdi |
collection | PubMed |
description | The title compound, [Cu(C(23)H(24)N(2)O(2))] or [Cu{(BA)(2)pn}], where (BA)(2)pn is 1,1′-diphenyl-3,3′-(propane-1,3-diyldinitrilo)dibut-1-enolate, is a mononuclear copper(II) complex, located on a twofold axis. The four-coordinate Cu(II) atom is in a tetrahedrally distorted square plane defined by the N and O atoms of the Schiff base ligand. In the tetradentate ligand, the two chelate rings are twisted relative to each other, making a dihedral angle of 36.57 (3)°. |
format | Text |
id | pubmed-2968291 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29682912010-12-30 [1,1′-Diphenyl-3,3′-(propane-1,3-diyldinitrilo)dibut-1-enolato]copper(II) Salehi, Mehdi Meghdadi, Soraia Amirnasr, Mehdi Mereiter, Kurt Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(C(23)H(24)N(2)O(2))] or [Cu{(BA)(2)pn}], where (BA)(2)pn is 1,1′-diphenyl-3,3′-(propane-1,3-diyldinitrilo)dibut-1-enolate, is a mononuclear copper(II) complex, located on a twofold axis. The four-coordinate Cu(II) atom is in a tetrahedrally distorted square plane defined by the N and O atoms of the Schiff base ligand. In the tetradentate ligand, the two chelate rings are twisted relative to each other, making a dihedral angle of 36.57 (3)°. International Union of Crystallography 2009-01-17 /pmc/articles/PMC2968291/ /pubmed/21581795 http://dx.doi.org/10.1107/S1600536809001081 Text en © Salehi et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Salehi, Mehdi Meghdadi, Soraia Amirnasr, Mehdi Mereiter, Kurt [1,1′-Diphenyl-3,3′-(propane-1,3-diyldinitrilo)dibut-1-enolato]copper(II) |
title | [1,1′-Diphenyl-3,3′-(propane-1,3-diyldinitrilo)dibut-1-enolato]copper(II) |
title_full | [1,1′-Diphenyl-3,3′-(propane-1,3-diyldinitrilo)dibut-1-enolato]copper(II) |
title_fullStr | [1,1′-Diphenyl-3,3′-(propane-1,3-diyldinitrilo)dibut-1-enolato]copper(II) |
title_full_unstemmed | [1,1′-Diphenyl-3,3′-(propane-1,3-diyldinitrilo)dibut-1-enolato]copper(II) |
title_short | [1,1′-Diphenyl-3,3′-(propane-1,3-diyldinitrilo)dibut-1-enolato]copper(II) |
title_sort | [1,1′-diphenyl-3,3′-(propane-1,3-diyldinitrilo)dibut-1-enolato]copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968291/ https://www.ncbi.nlm.nih.gov/pubmed/21581795 http://dx.doi.org/10.1107/S1600536809001081 |
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