Dibromidobis(triphenyl­arsine)palladium(II)

In the title compound, [PdBr(2)(C(18)H(15)As)(2)], the Pd(II) ion resides on a centre of symmetry and is coordinated by two As atoms [Pd—As = 2.4184 (3) Å] and two Br anions [Pd—Br = 2.4196 (3) Å] in a slightly distorted square-planar geometry [As—Pd—Br = 90.12 (1)°]. The crystal packing exhibits we...

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Detalles Bibliográficos
Autores principales: Kirsten, Leo, Steyl, Gideon
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968301/
https://www.ncbi.nlm.nih.gov/pubmed/21581811
http://dx.doi.org/10.1107/S1600536809001986
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author Kirsten, Leo
Steyl, Gideon
author_facet Kirsten, Leo
Steyl, Gideon
author_sort Kirsten, Leo
collection PubMed
description In the title compound, [PdBr(2)(C(18)H(15)As)(2)], the Pd(II) ion resides on a centre of symmetry and is coordinated by two As atoms [Pd—As = 2.4184 (3) Å] and two Br anions [Pd—Br = 2.4196 (3) Å] in a slightly distorted square-planar geometry [As—Pd—Br = 90.12 (1)°]. The crystal packing exhibits weak inter­molecular C—H⋯Br inter­actions.
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spelling pubmed-29683012010-12-30 Dibromidobis(triphenyl­arsine)palladium(II) Kirsten, Leo Steyl, Gideon Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [PdBr(2)(C(18)H(15)As)(2)], the Pd(II) ion resides on a centre of symmetry and is coordinated by two As atoms [Pd—As = 2.4184 (3) Å] and two Br anions [Pd—Br = 2.4196 (3) Å] in a slightly distorted square-planar geometry [As—Pd—Br = 90.12 (1)°]. The crystal packing exhibits weak inter­molecular C—H⋯Br inter­actions. International Union of Crystallography 2009-01-23 /pmc/articles/PMC2968301/ /pubmed/21581811 http://dx.doi.org/10.1107/S1600536809001986 Text en © Kirsten and Steyl 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kirsten, Leo
Steyl, Gideon
Dibromidobis(triphenyl­arsine)palladium(II)
title Dibromidobis(triphenyl­arsine)palladium(II)
title_full Dibromidobis(triphenyl­arsine)palladium(II)
title_fullStr Dibromidobis(triphenyl­arsine)palladium(II)
title_full_unstemmed Dibromidobis(triphenyl­arsine)palladium(II)
title_short Dibromidobis(triphenyl­arsine)palladium(II)
title_sort dibromidobis(triphenyl­arsine)palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968301/
https://www.ncbi.nlm.nih.gov/pubmed/21581811
http://dx.doi.org/10.1107/S1600536809001986
work_keys_str_mv AT kirstenleo dibromidobistriphenylarsinepalladiumii
AT steylgideon dibromidobistriphenylarsinepalladiumii

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