β-d-Altrose

The mol­ecule of the title compound, C(6)H(12)O(6), [systematic name: (2R,3S,4R,5R,6R)-6-(hydroxy­meth­yl)oxane-2,3,4,5-tetrol] adopts a (4) C (1) chair conformation with the anomeric hydroxyl group in the equatorial position. All hydroxyl groups act as donors and acceptors in hydrogen bonding and t...

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Autores principales: Watanabe, Yuji, Yoshida, Hiromi, Takeda, Kosei, Ishi, Tomohiko, Kamitori, Shigehiro
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968302/
https://www.ncbi.nlm.nih.gov/pubmed/21581893
http://dx.doi.org/10.1107/S1600536809000397
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author Watanabe, Yuji
Yoshida, Hiromi
Takeda, Kosei
Ishi, Tomohiko
Kamitori, Shigehiro
author_facet Watanabe, Yuji
Yoshida, Hiromi
Takeda, Kosei
Ishi, Tomohiko
Kamitori, Shigehiro
author_sort Watanabe, Yuji
collection PubMed
description The mol­ecule of the title compound, C(6)H(12)O(6), [systematic name: (2R,3S,4R,5R,6R)-6-(hydroxy­meth­yl)oxane-2,3,4,5-tetrol] adopts a (4) C (1) chair conformation with the anomeric hydroxyl group in the equatorial position. All hydroxyl groups act as donors and acceptors in hydrogen bonding and the mol­ecule is involved in ten inter­molecular O—H⋯O inter­actions [O⋯O = 2.672 (5)–2.776 (4) Å] with eight neighbouring mol­ecules. Two independent O—H⋯O—H⋯ helices extending along the z axis are found in this structure.
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spelling pubmed-29683022010-12-30 β-d-Altrose Watanabe, Yuji Yoshida, Hiromi Takeda, Kosei Ishi, Tomohiko Kamitori, Shigehiro Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(6)H(12)O(6), [systematic name: (2R,3S,4R,5R,6R)-6-(hydroxy­meth­yl)oxane-2,3,4,5-tetrol] adopts a (4) C (1) chair conformation with the anomeric hydroxyl group in the equatorial position. All hydroxyl groups act as donors and acceptors in hydrogen bonding and the mol­ecule is involved in ten inter­molecular O—H⋯O inter­actions [O⋯O = 2.672 (5)–2.776 (4) Å] with eight neighbouring mol­ecules. Two independent O—H⋯O—H⋯ helices extending along the z axis are found in this structure. International Union of Crystallography 2009-01-10 /pmc/articles/PMC2968302/ /pubmed/21581893 http://dx.doi.org/10.1107/S1600536809000397 Text en © Watanabe et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Watanabe, Yuji
Yoshida, Hiromi
Takeda, Kosei
Ishi, Tomohiko
Kamitori, Shigehiro
β-d-Altrose
title β-d-Altrose
title_full β-d-Altrose
title_fullStr β-d-Altrose
title_full_unstemmed β-d-Altrose
title_short β-d-Altrose
title_sort β-d-altrose
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968302/
https://www.ncbi.nlm.nih.gov/pubmed/21581893
http://dx.doi.org/10.1107/S1600536809000397
work_keys_str_mv AT watanabeyuji bdaltrose
AT yoshidahiromi bdaltrose
AT takedakosei bdaltrose
AT ishitomohiko bdaltrose
AT kamitorishigehiro bdaltrose

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