Holmium dodeca­iodidoiron-octa­hedro-hexa­holmium, {FeHo(6)}I(12)Ho

Single crystals of {FeHo(6)}I(12)Ho were obtained during the reaction of HoI(3) with metallic holmium and iron in a sealed tantalum container. The crystal structure consists of isolated holmium clusters encapsulating a single Fe atom, {FeHo(6)} ([Image: see text] symmetry). The rare earth metal atom...

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Detalles Bibliográficos
Autores principales: Daub, Kathrin, Meyer, Gerd
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968305/
https://www.ncbi.nlm.nih.gov/pubmed/21581743
http://dx.doi.org/10.1107/S1600536809001640
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author Daub, Kathrin
Meyer, Gerd
author_facet Daub, Kathrin
Meyer, Gerd
author_sort Daub, Kathrin
collection PubMed
description Single crystals of {FeHo(6)}I(12)Ho were obtained during the reaction of HoI(3) with metallic holmium and iron in a sealed tantalum container. The crystal structure consists of isolated holmium clusters encapsulating a single Fe atom, {FeHo(6)} ([Image: see text] symmetry). The rare earth metal atoms are surrounded by 12 edge-capping and six terminal iodide ligands that either connect the clusters to each other directly or via HoI(6) octa­hedra ([Image: see text] symmetry).
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spelling pubmed-29683052010-12-30 Holmium dodeca­iodidoiron-octa­hedro-hexa­holmium, {FeHo(6)}I(12)Ho Daub, Kathrin Meyer, Gerd Acta Crystallogr Sect E Struct Rep Online Inorganic Papers Single crystals of {FeHo(6)}I(12)Ho were obtained during the reaction of HoI(3) with metallic holmium and iron in a sealed tantalum container. The crystal structure consists of isolated holmium clusters encapsulating a single Fe atom, {FeHo(6)} ([Image: see text] symmetry). The rare earth metal atoms are surrounded by 12 edge-capping and six terminal iodide ligands that either connect the clusters to each other directly or via HoI(6) octa­hedra ([Image: see text] symmetry). International Union of Crystallography 2009-01-23 /pmc/articles/PMC2968305/ /pubmed/21581743 http://dx.doi.org/10.1107/S1600536809001640 Text en © Daub and Meyer 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Daub, Kathrin
Meyer, Gerd
Holmium dodeca­iodidoiron-octa­hedro-hexa­holmium, {FeHo(6)}I(12)Ho
title Holmium dodeca­iodidoiron-octa­hedro-hexa­holmium, {FeHo(6)}I(12)Ho
title_full Holmium dodeca­iodidoiron-octa­hedro-hexa­holmium, {FeHo(6)}I(12)Ho
title_fullStr Holmium dodeca­iodidoiron-octa­hedro-hexa­holmium, {FeHo(6)}I(12)Ho
title_full_unstemmed Holmium dodeca­iodidoiron-octa­hedro-hexa­holmium, {FeHo(6)}I(12)Ho
title_short Holmium dodeca­iodidoiron-octa­hedro-hexa­holmium, {FeHo(6)}I(12)Ho
title_sort holmium dodeca­iodidoiron-octa­hedro-hexa­holmium, {feho(6)}i(12)ho
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968305/
https://www.ncbi.nlm.nih.gov/pubmed/21581743
http://dx.doi.org/10.1107/S1600536809001640
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