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Hydronium (3-oxo-1-phosphono-1,3-dihydroisobenzofuran-1-yl)phosphonate
In the title compound, H(3)O(+)·C(8)H(7)O(8)P(2) (−), the anions form inversion dimmers by way of pairs of O—H⋯O hydrogen bonds involving the phosphonic functions and via the hydronium cation. Further O—H⋯O links involving the hydronium cation play a prominant part in the cohesion of the crystal s...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968306/ https://www.ncbi.nlm.nih.gov/pubmed/21581900 http://dx.doi.org/10.1107/S1600536809000907 |
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author | Barbey, Carole Retailleau, Pascal Guénin, Erwann Dupont, Nathalie |
author_facet | Barbey, Carole Retailleau, Pascal Guénin, Erwann Dupont, Nathalie |
author_sort | Barbey, Carole |
collection | PubMed |
description | In the title compound, H(3)O(+)·C(8)H(7)O(8)P(2) (−), the anions form inversion dimmers by way of pairs of O—H⋯O hydrogen bonds involving the phosphonic functions and via the hydronium cation. Further O—H⋯O links involving the hydronium cation play a prominant part in the cohesion of the crystal structure by building bridges between bisphosphonate pairs, forming infinite ribbons along the b-axis direction and by cross-linking these ribbons perpendicularly along the a-axis direction, forming an infinite three-dimensional hydrogen-bond network. The benzene ring and the C=O atoms of the furan ring are disordered over two sets of positions of equal occupancy. |
format | Text |
id | pubmed-2968306 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29683062010-12-30 Hydronium (3-oxo-1-phosphono-1,3-dihydroisobenzofuran-1-yl)phosphonate Barbey, Carole Retailleau, Pascal Guénin, Erwann Dupont, Nathalie Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, H(3)O(+)·C(8)H(7)O(8)P(2) (−), the anions form inversion dimmers by way of pairs of O—H⋯O hydrogen bonds involving the phosphonic functions and via the hydronium cation. Further O—H⋯O links involving the hydronium cation play a prominant part in the cohesion of the crystal structure by building bridges between bisphosphonate pairs, forming infinite ribbons along the b-axis direction and by cross-linking these ribbons perpendicularly along the a-axis direction, forming an infinite three-dimensional hydrogen-bond network. The benzene ring and the C=O atoms of the furan ring are disordered over two sets of positions of equal occupancy. International Union of Crystallography 2009-01-10 /pmc/articles/PMC2968306/ /pubmed/21581900 http://dx.doi.org/10.1107/S1600536809000907 Text en © Barbey et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Barbey, Carole Retailleau, Pascal Guénin, Erwann Dupont, Nathalie Hydronium (3-oxo-1-phosphono-1,3-dihydroisobenzofuran-1-yl)phosphonate |
title | Hydronium (3-oxo-1-phosphono-1,3-dihydroisobenzofuran-1-yl)phosphonate |
title_full | Hydronium (3-oxo-1-phosphono-1,3-dihydroisobenzofuran-1-yl)phosphonate |
title_fullStr | Hydronium (3-oxo-1-phosphono-1,3-dihydroisobenzofuran-1-yl)phosphonate |
title_full_unstemmed | Hydronium (3-oxo-1-phosphono-1,3-dihydroisobenzofuran-1-yl)phosphonate |
title_short | Hydronium (3-oxo-1-phosphono-1,3-dihydroisobenzofuran-1-yl)phosphonate |
title_sort | hydronium (3-oxo-1-phosphono-1,3-dihydroisobenzofuran-1-yl)phosphonate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968306/ https://www.ncbi.nlm.nih.gov/pubmed/21581900 http://dx.doi.org/10.1107/S1600536809000907 |
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