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Hydro­nium (3-oxo-1-phosphono-1,3-dihydro­isobenzofuran-1-yl)phospho­nate

In the title compound, H(3)O(+)·C(8)H(7)O(8)P(2) (−), the anions form inversion dimmers by way of pairs of O—H⋯O hydrogen bonds involving the phospho­nic functions and via the hydro­nium cation. Further O—H⋯O links involving the hydronium cation play a prominant part in the cohesion of the crystal s...

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Detalles Bibliográficos
Autores principales: Barbey, Carole, Retailleau, Pascal, Guénin, Erwann, Dupont, Nathalie
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968306/
https://www.ncbi.nlm.nih.gov/pubmed/21581900
http://dx.doi.org/10.1107/S1600536809000907
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author Barbey, Carole
Retailleau, Pascal
Guénin, Erwann
Dupont, Nathalie
author_facet Barbey, Carole
Retailleau, Pascal
Guénin, Erwann
Dupont, Nathalie
author_sort Barbey, Carole
collection PubMed
description In the title compound, H(3)O(+)·C(8)H(7)O(8)P(2) (−), the anions form inversion dimmers by way of pairs of O—H⋯O hydrogen bonds involving the phospho­nic functions and via the hydro­nium cation. Further O—H⋯O links involving the hydronium cation play a prominant part in the cohesion of the crystal structure by building bridges between bis­phospho­nate pairs, forming infinite ribbons along the b-axis direction and by cross-linking these ribbons perpendicularly along the a-axis direction, forming an infinite three-dimensional hydrogen-bond network. The benzene ring and the C=O atoms of the furan ring are disordered over two sets of positions of equal occupancy.
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spelling pubmed-29683062010-12-30 Hydro­nium (3-oxo-1-phosphono-1,3-dihydro­isobenzofuran-1-yl)phospho­nate Barbey, Carole Retailleau, Pascal Guénin, Erwann Dupont, Nathalie Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, H(3)O(+)·C(8)H(7)O(8)P(2) (−), the anions form inversion dimmers by way of pairs of O—H⋯O hydrogen bonds involving the phospho­nic functions and via the hydro­nium cation. Further O—H⋯O links involving the hydronium cation play a prominant part in the cohesion of the crystal structure by building bridges between bis­phospho­nate pairs, forming infinite ribbons along the b-axis direction and by cross-linking these ribbons perpendicularly along the a-axis direction, forming an infinite three-dimensional hydrogen-bond network. The benzene ring and the C=O atoms of the furan ring are disordered over two sets of positions of equal occupancy. International Union of Crystallography 2009-01-10 /pmc/articles/PMC2968306/ /pubmed/21581900 http://dx.doi.org/10.1107/S1600536809000907 Text en © Barbey et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Barbey, Carole
Retailleau, Pascal
Guénin, Erwann
Dupont, Nathalie
Hydro­nium (3-oxo-1-phosphono-1,3-dihydro­isobenzofuran-1-yl)phospho­nate
title Hydro­nium (3-oxo-1-phosphono-1,3-dihydro­isobenzofuran-1-yl)phospho­nate
title_full Hydro­nium (3-oxo-1-phosphono-1,3-dihydro­isobenzofuran-1-yl)phospho­nate
title_fullStr Hydro­nium (3-oxo-1-phosphono-1,3-dihydro­isobenzofuran-1-yl)phospho­nate
title_full_unstemmed Hydro­nium (3-oxo-1-phosphono-1,3-dihydro­isobenzofuran-1-yl)phospho­nate
title_short Hydro­nium (3-oxo-1-phosphono-1,3-dihydro­isobenzofuran-1-yl)phospho­nate
title_sort hydro­nium (3-oxo-1-phosphono-1,3-dihydro­isobenzofuran-1-yl)phospho­nate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968306/
https://www.ncbi.nlm.nih.gov/pubmed/21581900
http://dx.doi.org/10.1107/S1600536809000907
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