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catena-Poly[dieth­yl(2-hydroxy­ethyl)­ammonium [[tetra-μ-acetato-κ(8) O:O′-dicuprate(II)(Cu—Cu)]-μ-acetato-κ(2) O:O′] dichloro­methane solvate]

The title compound, {(C(6)H(16)NO)[Cu(2)(CH(3)COO)(5)]·CH(2)Cl(2)}(n), consists of acetate-bridged Cu(2)(CH(3)COO)(4) units that are connected via another acetate anion at each terminus to form infinite anionic [{Cu(2)(CH(3)COO)(4)}(CH(3)COO)](n) chains along [100]. The connecting acetate is hydroge...

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Detalles Bibliográficos
Autores principales: Shahid, Muhammad, Mazhar, Muhammad, O’Brien, Paul, Afzaal, Mohammad, Raftery, James
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968312/
https://www.ncbi.nlm.nih.gov/pubmed/21581773
http://dx.doi.org/10.1107/S1600536808044048
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author Shahid, Muhammad
Mazhar, Muhammad
O’Brien, Paul
Afzaal, Mohammad
Raftery, James
author_facet Shahid, Muhammad
Mazhar, Muhammad
O’Brien, Paul
Afzaal, Mohammad
Raftery, James
author_sort Shahid, Muhammad
collection PubMed
description The title compound, {(C(6)H(16)NO)[Cu(2)(CH(3)COO)(5)]·CH(2)Cl(2)}(n), consists of acetate-bridged Cu(2)(CH(3)COO)(4) units that are connected via another acetate anion at each terminus to form infinite anionic [{Cu(2)(CH(3)COO)(4)}(CH(3)COO)](n) chains along [100]. The connecting acetate is hydrogen bonded to the dieth­yl(2-hydroxy­ethyl)ammonium cation, and the dichloro­methane solvent mol­ecule fills the remaining voids in the structure. The O—Cu—Cu angles along the polymeric chain are nearly linear [175.49 (5)°], but individual O—Cu—Cu—O units along the chain are bent and rotated against each other at the bridging acetate ion. Translation of each Cu(2)(CH(3)COO)(4) unit along the chain, represented by the least-squares plane of the two copper ions along with four of the acetate O atoms, rotated these units by 35.16 (3)°.
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spelling pubmed-29683122010-12-30 catena-Poly[dieth­yl(2-hydroxy­ethyl)­ammonium [[tetra-μ-acetato-κ(8) O:O′-dicuprate(II)(Cu—Cu)]-μ-acetato-κ(2) O:O′] dichloro­methane solvate] Shahid, Muhammad Mazhar, Muhammad O’Brien, Paul Afzaal, Mohammad Raftery, James Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {(C(6)H(16)NO)[Cu(2)(CH(3)COO)(5)]·CH(2)Cl(2)}(n), consists of acetate-bridged Cu(2)(CH(3)COO)(4) units that are connected via another acetate anion at each terminus to form infinite anionic [{Cu(2)(CH(3)COO)(4)}(CH(3)COO)](n) chains along [100]. The connecting acetate is hydrogen bonded to the dieth­yl(2-hydroxy­ethyl)ammonium cation, and the dichloro­methane solvent mol­ecule fills the remaining voids in the structure. The O—Cu—Cu angles along the polymeric chain are nearly linear [175.49 (5)°], but individual O—Cu—Cu—O units along the chain are bent and rotated against each other at the bridging acetate ion. Translation of each Cu(2)(CH(3)COO)(4) unit along the chain, represented by the least-squares plane of the two copper ions along with four of the acetate O atoms, rotated these units by 35.16 (3)°. International Union of Crystallography 2009-01-08 /pmc/articles/PMC2968312/ /pubmed/21581773 http://dx.doi.org/10.1107/S1600536808044048 Text en © Shahid et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shahid, Muhammad
Mazhar, Muhammad
O’Brien, Paul
Afzaal, Mohammad
Raftery, James
catena-Poly[dieth­yl(2-hydroxy­ethyl)­ammonium [[tetra-μ-acetato-κ(8) O:O′-dicuprate(II)(Cu—Cu)]-μ-acetato-κ(2) O:O′] dichloro­methane solvate]
title catena-Poly[dieth­yl(2-hydroxy­ethyl)­ammonium [[tetra-μ-acetato-κ(8) O:O′-dicuprate(II)(Cu—Cu)]-μ-acetato-κ(2) O:O′] dichloro­methane solvate]
title_full catena-Poly[dieth­yl(2-hydroxy­ethyl)­ammonium [[tetra-μ-acetato-κ(8) O:O′-dicuprate(II)(Cu—Cu)]-μ-acetato-κ(2) O:O′] dichloro­methane solvate]
title_fullStr catena-Poly[dieth­yl(2-hydroxy­ethyl)­ammonium [[tetra-μ-acetato-κ(8) O:O′-dicuprate(II)(Cu—Cu)]-μ-acetato-κ(2) O:O′] dichloro­methane solvate]
title_full_unstemmed catena-Poly[dieth­yl(2-hydroxy­ethyl)­ammonium [[tetra-μ-acetato-κ(8) O:O′-dicuprate(II)(Cu—Cu)]-μ-acetato-κ(2) O:O′] dichloro­methane solvate]
title_short catena-Poly[dieth­yl(2-hydroxy­ethyl)­ammonium [[tetra-μ-acetato-κ(8) O:O′-dicuprate(II)(Cu—Cu)]-μ-acetato-κ(2) O:O′] dichloro­methane solvate]
title_sort catena-poly[dieth­yl(2-hydroxy­ethyl)­ammonium [[tetra-μ-acetato-κ(8) o:o′-dicuprate(ii)(cu—cu)]-μ-acetato-κ(2) o:o′] dichloro­methane solvate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968312/
https://www.ncbi.nlm.nih.gov/pubmed/21581773
http://dx.doi.org/10.1107/S1600536808044048
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