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catena-Poly[diethyl(2-hydroxyethyl)ammonium [[tetra-μ-acetato-κ(8) O:O′-dicuprate(II)(Cu—Cu)]-μ-acetato-κ(2) O:O′] dichloromethane solvate]
The title compound, {(C(6)H(16)NO)[Cu(2)(CH(3)COO)(5)]·CH(2)Cl(2)}(n), consists of acetate-bridged Cu(2)(CH(3)COO)(4) units that are connected via another acetate anion at each terminus to form infinite anionic [{Cu(2)(CH(3)COO)(4)}(CH(3)COO)](n) chains along [100]. The connecting acetate is hydroge...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968312/ https://www.ncbi.nlm.nih.gov/pubmed/21581773 http://dx.doi.org/10.1107/S1600536808044048 |
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author | Shahid, Muhammad Mazhar, Muhammad O’Brien, Paul Afzaal, Mohammad Raftery, James |
author_facet | Shahid, Muhammad Mazhar, Muhammad O’Brien, Paul Afzaal, Mohammad Raftery, James |
author_sort | Shahid, Muhammad |
collection | PubMed |
description | The title compound, {(C(6)H(16)NO)[Cu(2)(CH(3)COO)(5)]·CH(2)Cl(2)}(n), consists of acetate-bridged Cu(2)(CH(3)COO)(4) units that are connected via another acetate anion at each terminus to form infinite anionic [{Cu(2)(CH(3)COO)(4)}(CH(3)COO)](n) chains along [100]. The connecting acetate is hydrogen bonded to the diethyl(2-hydroxyethyl)ammonium cation, and the dichloromethane solvent molecule fills the remaining voids in the structure. The O—Cu—Cu angles along the polymeric chain are nearly linear [175.49 (5)°], but individual O—Cu—Cu—O units along the chain are bent and rotated against each other at the bridging acetate ion. Translation of each Cu(2)(CH(3)COO)(4) unit along the chain, represented by the least-squares plane of the two copper ions along with four of the acetate O atoms, rotated these units by 35.16 (3)°. |
format | Text |
id | pubmed-2968312 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29683122010-12-30 catena-Poly[diethyl(2-hydroxyethyl)ammonium [[tetra-μ-acetato-κ(8) O:O′-dicuprate(II)(Cu—Cu)]-μ-acetato-κ(2) O:O′] dichloromethane solvate] Shahid, Muhammad Mazhar, Muhammad O’Brien, Paul Afzaal, Mohammad Raftery, James Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {(C(6)H(16)NO)[Cu(2)(CH(3)COO)(5)]·CH(2)Cl(2)}(n), consists of acetate-bridged Cu(2)(CH(3)COO)(4) units that are connected via another acetate anion at each terminus to form infinite anionic [{Cu(2)(CH(3)COO)(4)}(CH(3)COO)](n) chains along [100]. The connecting acetate is hydrogen bonded to the diethyl(2-hydroxyethyl)ammonium cation, and the dichloromethane solvent molecule fills the remaining voids in the structure. The O—Cu—Cu angles along the polymeric chain are nearly linear [175.49 (5)°], but individual O—Cu—Cu—O units along the chain are bent and rotated against each other at the bridging acetate ion. Translation of each Cu(2)(CH(3)COO)(4) unit along the chain, represented by the least-squares plane of the two copper ions along with four of the acetate O atoms, rotated these units by 35.16 (3)°. International Union of Crystallography 2009-01-08 /pmc/articles/PMC2968312/ /pubmed/21581773 http://dx.doi.org/10.1107/S1600536808044048 Text en © Shahid et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shahid, Muhammad Mazhar, Muhammad O’Brien, Paul Afzaal, Mohammad Raftery, James catena-Poly[diethyl(2-hydroxyethyl)ammonium [[tetra-μ-acetato-κ(8) O:O′-dicuprate(II)(Cu—Cu)]-μ-acetato-κ(2) O:O′] dichloromethane solvate] |
title |
catena-Poly[diethyl(2-hydroxyethyl)ammonium [[tetra-μ-acetato-κ(8)
O:O′-dicuprate(II)(Cu—Cu)]-μ-acetato-κ(2)
O:O′] dichloromethane solvate] |
title_full |
catena-Poly[diethyl(2-hydroxyethyl)ammonium [[tetra-μ-acetato-κ(8)
O:O′-dicuprate(II)(Cu—Cu)]-μ-acetato-κ(2)
O:O′] dichloromethane solvate] |
title_fullStr |
catena-Poly[diethyl(2-hydroxyethyl)ammonium [[tetra-μ-acetato-κ(8)
O:O′-dicuprate(II)(Cu—Cu)]-μ-acetato-κ(2)
O:O′] dichloromethane solvate] |
title_full_unstemmed |
catena-Poly[diethyl(2-hydroxyethyl)ammonium [[tetra-μ-acetato-κ(8)
O:O′-dicuprate(II)(Cu—Cu)]-μ-acetato-κ(2)
O:O′] dichloromethane solvate] |
title_short |
catena-Poly[diethyl(2-hydroxyethyl)ammonium [[tetra-μ-acetato-κ(8)
O:O′-dicuprate(II)(Cu—Cu)]-μ-acetato-κ(2)
O:O′] dichloromethane solvate] |
title_sort | catena-poly[diethyl(2-hydroxyethyl)ammonium [[tetra-μ-acetato-κ(8)
o:o′-dicuprate(ii)(cu—cu)]-μ-acetato-κ(2)
o:o′] dichloromethane solvate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968312/ https://www.ncbi.nlm.nih.gov/pubmed/21581773 http://dx.doi.org/10.1107/S1600536808044048 |
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