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[N,N′-Bis(4-chlorobenzylidene)-2,2-dimethylpropane-1,3-diamine-κ(2) N,N′]iodidocopper(I)

The mol­ecule of the title compound, [CuI(C(19)H(20)Cl(2)N(2))], lies across a crystallographic mirror plane. The coordination around the copper centre is distorted trigonal planar, with a bite angle of 94.40 (7)°. A six-membered chelate ring is formed by the coordination of iminic N atoms of the bi...

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Detalles Bibliográficos
Autores principales: Kia, Reza, Fun, Hoong-Kun, Kargar, Hadi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968316/
https://www.ncbi.nlm.nih.gov/pubmed/21581796
http://dx.doi.org/10.1107/S160053680900107X
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author Kia, Reza
Fun, Hoong-Kun
Kargar, Hadi
author_facet Kia, Reza
Fun, Hoong-Kun
Kargar, Hadi
author_sort Kia, Reza
collection PubMed
description The mol­ecule of the title compound, [CuI(C(19)H(20)Cl(2)N(2))], lies across a crystallographic mirror plane. The coordination around the copper centre is distorted trigonal planar, with a bite angle of 94.40 (7)°. A six-membered chelate ring is formed by the coordination of iminic N atoms of the bidentate ligand to the Cu(I) atom, adopting a chair conformation. This conformation is required if the local symmetry of the metal coordination site is in accordance with a mirror plane that passes through the metal atom normal to the line connecting the N atoms. The dihedral angle between the benzene rings is 78.66 (5)°. The crystal structure is stabilized by weak inter­molecular C—H⋯π inter­actions, which link the mol­ecules into chains along the b axis.
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spelling pubmed-29683162010-12-30 [N,N′-Bis(4-chlorobenzylidene)-2,2-dimethylpropane-1,3-diamine-κ(2) N,N′]iodidocopper(I) Kia, Reza Fun, Hoong-Kun Kargar, Hadi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The mol­ecule of the title compound, [CuI(C(19)H(20)Cl(2)N(2))], lies across a crystallographic mirror plane. The coordination around the copper centre is distorted trigonal planar, with a bite angle of 94.40 (7)°. A six-membered chelate ring is formed by the coordination of iminic N atoms of the bidentate ligand to the Cu(I) atom, adopting a chair conformation. This conformation is required if the local symmetry of the metal coordination site is in accordance with a mirror plane that passes through the metal atom normal to the line connecting the N atoms. The dihedral angle between the benzene rings is 78.66 (5)°. The crystal structure is stabilized by weak inter­molecular C—H⋯π inter­actions, which link the mol­ecules into chains along the b axis. International Union of Crystallography 2009-01-17 /pmc/articles/PMC2968316/ /pubmed/21581796 http://dx.doi.org/10.1107/S160053680900107X Text en © Kia et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kia, Reza
Fun, Hoong-Kun
Kargar, Hadi
[N,N′-Bis(4-chlorobenzylidene)-2,2-dimethylpropane-1,3-diamine-κ(2) N,N′]iodidocopper(I)
title [N,N′-Bis(4-chlorobenzylidene)-2,2-dimethylpropane-1,3-diamine-κ(2) N,N′]iodidocopper(I)
title_full [N,N′-Bis(4-chlorobenzylidene)-2,2-dimethylpropane-1,3-diamine-κ(2) N,N′]iodidocopper(I)
title_fullStr [N,N′-Bis(4-chlorobenzylidene)-2,2-dimethylpropane-1,3-diamine-κ(2) N,N′]iodidocopper(I)
title_full_unstemmed [N,N′-Bis(4-chlorobenzylidene)-2,2-dimethylpropane-1,3-diamine-κ(2) N,N′]iodidocopper(I)
title_short [N,N′-Bis(4-chlorobenzylidene)-2,2-dimethylpropane-1,3-diamine-κ(2) N,N′]iodidocopper(I)
title_sort [n,n′-bis(4-chlorobenzylidene)-2,2-dimethylpropane-1,3-diamine-κ(2) n,n′]iodidocopper(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968316/
https://www.ncbi.nlm.nih.gov/pubmed/21581796
http://dx.doi.org/10.1107/S160053680900107X
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AT kargarhadi nnbis4chlorobenzylidene22dimethylpropane13diaminek2nniodidocopperi