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[N,N′-Bis(4-chlorobenzylidene)-2,2-dimethylpropane-1,3-diamine-κ(2) N,N′]iodidocopper(I)
The molecule of the title compound, [CuI(C(19)H(20)Cl(2)N(2))], lies across a crystallographic mirror plane. The coordination around the copper centre is distorted trigonal planar, with a bite angle of 94.40 (7)°. A six-membered chelate ring is formed by the coordination of iminic N atoms of the bi...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968316/ https://www.ncbi.nlm.nih.gov/pubmed/21581796 http://dx.doi.org/10.1107/S160053680900107X |
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author | Kia, Reza Fun, Hoong-Kun Kargar, Hadi |
author_facet | Kia, Reza Fun, Hoong-Kun Kargar, Hadi |
author_sort | Kia, Reza |
collection | PubMed |
description | The molecule of the title compound, [CuI(C(19)H(20)Cl(2)N(2))], lies across a crystallographic mirror plane. The coordination around the copper centre is distorted trigonal planar, with a bite angle of 94.40 (7)°. A six-membered chelate ring is formed by the coordination of iminic N atoms of the bidentate ligand to the Cu(I) atom, adopting a chair conformation. This conformation is required if the local symmetry of the metal coordination site is in accordance with a mirror plane that passes through the metal atom normal to the line connecting the N atoms. The dihedral angle between the benzene rings is 78.66 (5)°. The crystal structure is stabilized by weak intermolecular C—H⋯π interactions, which link the molecules into chains along the b axis. |
format | Text |
id | pubmed-2968316 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29683162010-12-30 [N,N′-Bis(4-chlorobenzylidene)-2,2-dimethylpropane-1,3-diamine-κ(2) N,N′]iodidocopper(I) Kia, Reza Fun, Hoong-Kun Kargar, Hadi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The molecule of the title compound, [CuI(C(19)H(20)Cl(2)N(2))], lies across a crystallographic mirror plane. The coordination around the copper centre is distorted trigonal planar, with a bite angle of 94.40 (7)°. A six-membered chelate ring is formed by the coordination of iminic N atoms of the bidentate ligand to the Cu(I) atom, adopting a chair conformation. This conformation is required if the local symmetry of the metal coordination site is in accordance with a mirror plane that passes through the metal atom normal to the line connecting the N atoms. The dihedral angle between the benzene rings is 78.66 (5)°. The crystal structure is stabilized by weak intermolecular C—H⋯π interactions, which link the molecules into chains along the b axis. International Union of Crystallography 2009-01-17 /pmc/articles/PMC2968316/ /pubmed/21581796 http://dx.doi.org/10.1107/S160053680900107X Text en © Kia et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Kia, Reza Fun, Hoong-Kun Kargar, Hadi [N,N′-Bis(4-chlorobenzylidene)-2,2-dimethylpropane-1,3-diamine-κ(2) N,N′]iodidocopper(I) |
title | [N,N′-Bis(4-chlorobenzylidene)-2,2-dimethylpropane-1,3-diamine-κ(2)
N,N′]iodidocopper(I) |
title_full | [N,N′-Bis(4-chlorobenzylidene)-2,2-dimethylpropane-1,3-diamine-κ(2)
N,N′]iodidocopper(I) |
title_fullStr | [N,N′-Bis(4-chlorobenzylidene)-2,2-dimethylpropane-1,3-diamine-κ(2)
N,N′]iodidocopper(I) |
title_full_unstemmed | [N,N′-Bis(4-chlorobenzylidene)-2,2-dimethylpropane-1,3-diamine-κ(2)
N,N′]iodidocopper(I) |
title_short | [N,N′-Bis(4-chlorobenzylidene)-2,2-dimethylpropane-1,3-diamine-κ(2)
N,N′]iodidocopper(I) |
title_sort | [n,n′-bis(4-chlorobenzylidene)-2,2-dimethylpropane-1,3-diamine-κ(2)
n,n′]iodidocopper(i) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968316/ https://www.ncbi.nlm.nih.gov/pubmed/21581796 http://dx.doi.org/10.1107/S160053680900107X |
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