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[3,3′-Bis(1-naphthylmethyl)-1,1′-(2,2′-oxy­diethyl­ene)bis­(imidazol-2-yl­idene)]mercury(II) bis­(hexa­fluorido­phosphate) acetonitrile solvate

In the title compound, [Hg(C(32)H(30)N(4)O)](PF(6))(2)·CH(3)CN, the mercury(II) ion is coordinated by two carbene C atoms [Hg—C = 2.060 (6) and 2.066 (6) Å] and one ether O atom [Hg—O = 2.561 (5) Å] in a distorted T-shaped geometry with a C—Hg—C angle of 166.3 (3)°. One hexa­fluorido­phosphate anion...

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Detalles Bibliográficos
Autores principales: Guo, Wen-Yan, Dong, Gui-Ying
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968318/
https://www.ncbi.nlm.nih.gov/pubmed/21581810
http://dx.doi.org/10.1107/S1600536809001743
Descripción
Sumario:In the title compound, [Hg(C(32)H(30)N(4)O)](PF(6))(2)·CH(3)CN, the mercury(II) ion is coordinated by two carbene C atoms [Hg—C = 2.060 (6) and 2.066 (6) Å] and one ether O atom [Hg—O = 2.561 (5) Å] in a distorted T-shaped geometry with a C—Hg—C angle of 166.3 (3)°. One hexa­fluorido­phosphate anion is rotationally disordered between two orientations with an approximate ratio of 2:1. The crystal packing exhibits weak inter­molecular C—H⋯F and C—H⋯N inter­actions.