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[3,3′-Bis(1-naphthylmethyl)-1,1′-(2,2′-oxydiethylene)bis(imidazol-2-ylidene)]mercury(II) bis(hexafluoridophosphate) acetonitrile solvate
In the title compound, [Hg(C(32)H(30)N(4)O)](PF(6))(2)·CH(3)CN, the mercury(II) ion is coordinated by two carbene C atoms [Hg—C = 2.060 (6) and 2.066 (6) Å] and one ether O atom [Hg—O = 2.561 (5) Å] in a distorted T-shaped geometry with a C—Hg—C angle of 166.3 (3)°. One hexafluoridophosphate anion...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968318/ https://www.ncbi.nlm.nih.gov/pubmed/21581810 http://dx.doi.org/10.1107/S1600536809001743 |
| _version_ | 1782189839115878400 |
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| author | Guo, Wen-Yan Dong, Gui-Ying |
| author_facet | Guo, Wen-Yan Dong, Gui-Ying |
| author_sort | Guo, Wen-Yan |
| collection | PubMed |
| description | In the title compound, [Hg(C(32)H(30)N(4)O)](PF(6))(2)·CH(3)CN, the mercury(II) ion is coordinated by two carbene C atoms [Hg—C = 2.060 (6) and 2.066 (6) Å] and one ether O atom [Hg—O = 2.561 (5) Å] in a distorted T-shaped geometry with a C—Hg—C angle of 166.3 (3)°. One hexafluoridophosphate anion is rotationally disordered between two orientations with an approximate ratio of 2:1. The crystal packing exhibits weak intermolecular C—H⋯F and C—H⋯N interactions. |
| format | Text |
| id | pubmed-2968318 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29683182010-12-30 [3,3′-Bis(1-naphthylmethyl)-1,1′-(2,2′-oxydiethylene)bis(imidazol-2-ylidene)]mercury(II) bis(hexafluoridophosphate) acetonitrile solvate Guo, Wen-Yan Dong, Gui-Ying Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Hg(C(32)H(30)N(4)O)](PF(6))(2)·CH(3)CN, the mercury(II) ion is coordinated by two carbene C atoms [Hg—C = 2.060 (6) and 2.066 (6) Å] and one ether O atom [Hg—O = 2.561 (5) Å] in a distorted T-shaped geometry with a C—Hg—C angle of 166.3 (3)°. One hexafluoridophosphate anion is rotationally disordered between two orientations with an approximate ratio of 2:1. The crystal packing exhibits weak intermolecular C—H⋯F and C—H⋯N interactions. International Union of Crystallography 2009-01-23 /pmc/articles/PMC2968318/ /pubmed/21581810 http://dx.doi.org/10.1107/S1600536809001743 Text en © Guo and Dong 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Guo, Wen-Yan Dong, Gui-Ying [3,3′-Bis(1-naphthylmethyl)-1,1′-(2,2′-oxydiethylene)bis(imidazol-2-ylidene)]mercury(II) bis(hexafluoridophosphate) acetonitrile solvate |
| title | [3,3′-Bis(1-naphthylmethyl)-1,1′-(2,2′-oxydiethylene)bis(imidazol-2-ylidene)]mercury(II) bis(hexafluoridophosphate) acetonitrile solvate |
| title_full | [3,3′-Bis(1-naphthylmethyl)-1,1′-(2,2′-oxydiethylene)bis(imidazol-2-ylidene)]mercury(II) bis(hexafluoridophosphate) acetonitrile solvate |
| title_fullStr | [3,3′-Bis(1-naphthylmethyl)-1,1′-(2,2′-oxydiethylene)bis(imidazol-2-ylidene)]mercury(II) bis(hexafluoridophosphate) acetonitrile solvate |
| title_full_unstemmed | [3,3′-Bis(1-naphthylmethyl)-1,1′-(2,2′-oxydiethylene)bis(imidazol-2-ylidene)]mercury(II) bis(hexafluoridophosphate) acetonitrile solvate |
| title_short | [3,3′-Bis(1-naphthylmethyl)-1,1′-(2,2′-oxydiethylene)bis(imidazol-2-ylidene)]mercury(II) bis(hexafluoridophosphate) acetonitrile solvate |
| title_sort | [3,3′-bis(1-naphthylmethyl)-1,1′-(2,2′-oxydiethylene)bis(imidazol-2-ylidene)]mercury(ii) bis(hexafluoridophosphate) acetonitrile solvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968318/ https://www.ncbi.nlm.nih.gov/pubmed/21581810 http://dx.doi.org/10.1107/S1600536809001743 |
| work_keys_str_mv | AT guowenyan 33bis1naphthylmethyl1122oxydiethylenebisimidazol2ylidenemercuryiibishexafluoridophosphateacetonitrilesolvate AT dongguiying 33bis1naphthylmethyl1122oxydiethylenebisimidazol2ylidenemercuryiibishexafluoridophosphateacetonitrilesolvate |