Cargando…

Dimethyl 2,2′-[(4-oxo-2-phenyl-4H-chromene-5,7-di­yl)di­oxy]diacetate: a less densely packed polymorph

The title mol­ecule, C(21)H(18)O(8), crystallizes in two crystal polymorphs, see also Nallasivam, Nethaji, Vembu & Jaswant [Acta Cryst. (2009), E65, o312–o313]. The main difference between the two polymorphs is in the conformation of the oxomethyl­acetate groups with regard to the almost planar...

Descripción completa

Detalles Bibliográficos
Autores principales: Nallasivam, Angannan, Nethaji, Munirathinam, Vembu, Nagarajan, Jaswant, Buckle, Sulochana, Nagarajan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968320/
https://www.ncbi.nlm.nih.gov/pubmed/21581921
http://dx.doi.org/10.1107/S1600536809001019
_version_ 1782189839693643776
author Nallasivam, Angannan
Nethaji, Munirathinam
Vembu, Nagarajan
Jaswant, Buckle
Sulochana, Nagarajan
author_facet Nallasivam, Angannan
Nethaji, Munirathinam
Vembu, Nagarajan
Jaswant, Buckle
Sulochana, Nagarajan
author_sort Nallasivam, Angannan
collection PubMed
description The title mol­ecule, C(21)H(18)O(8), crystallizes in two crystal polymorphs, see also Nallasivam, Nethaji, Vembu & Jaswant [Acta Cryst. (2009), E65, o312–o313]. The main difference between the two polymorphs is in the conformation of the oxomethyl­acetate groups with regard to the almost planar [total puckering amplitude 0.047 (2) Å] chromene ring. In the title compound, the best planes of the oxomethyl­acetate groups through the non-H atoms are almost perpendicular to the chromene ring [making dihedral angles of 89.61 (6) and 80.59 (5)°], while in the second polymorph the mol­ecules are close to planar. Both crystal structures are stabilized by C—H⋯O.
format Text
id pubmed-2968320
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29683202010-12-30 Dimethyl 2,2′-[(4-oxo-2-phenyl-4H-chromene-5,7-di­yl)di­oxy]diacetate: a less densely packed polymorph Nallasivam, Angannan Nethaji, Munirathinam Vembu, Nagarajan Jaswant, Buckle Sulochana, Nagarajan Acta Crystallogr Sect E Struct Rep Online Organic Papers The title mol­ecule, C(21)H(18)O(8), crystallizes in two crystal polymorphs, see also Nallasivam, Nethaji, Vembu & Jaswant [Acta Cryst. (2009), E65, o312–o313]. The main difference between the two polymorphs is in the conformation of the oxomethyl­acetate groups with regard to the almost planar [total puckering amplitude 0.047 (2) Å] chromene ring. In the title compound, the best planes of the oxomethyl­acetate groups through the non-H atoms are almost perpendicular to the chromene ring [making dihedral angles of 89.61 (6) and 80.59 (5)°], while in the second polymorph the mol­ecules are close to planar. Both crystal structures are stabilized by C—H⋯O. International Union of Crystallography 2009-01-14 /pmc/articles/PMC2968320/ /pubmed/21581921 http://dx.doi.org/10.1107/S1600536809001019 Text en © Nallasivam et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Nallasivam, Angannan
Nethaji, Munirathinam
Vembu, Nagarajan
Jaswant, Buckle
Sulochana, Nagarajan
Dimethyl 2,2′-[(4-oxo-2-phenyl-4H-chromene-5,7-di­yl)di­oxy]diacetate: a less densely packed polymorph
title Dimethyl 2,2′-[(4-oxo-2-phenyl-4H-chromene-5,7-di­yl)di­oxy]diacetate: a less densely packed polymorph
title_full Dimethyl 2,2′-[(4-oxo-2-phenyl-4H-chromene-5,7-di­yl)di­oxy]diacetate: a less densely packed polymorph
title_fullStr Dimethyl 2,2′-[(4-oxo-2-phenyl-4H-chromene-5,7-di­yl)di­oxy]diacetate: a less densely packed polymorph
title_full_unstemmed Dimethyl 2,2′-[(4-oxo-2-phenyl-4H-chromene-5,7-di­yl)di­oxy]diacetate: a less densely packed polymorph
title_short Dimethyl 2,2′-[(4-oxo-2-phenyl-4H-chromene-5,7-di­yl)di­oxy]diacetate: a less densely packed polymorph
title_sort dimethyl 2,2′-[(4-oxo-2-phenyl-4h-chromene-5,7-di­yl)di­oxy]diacetate: a less densely packed polymorph
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968320/
https://www.ncbi.nlm.nih.gov/pubmed/21581921
http://dx.doi.org/10.1107/S1600536809001019
work_keys_str_mv AT nallasivamangannan dimethyl224oxo2phenyl4hchromene57diyldioxydiacetatealessdenselypackedpolymorph
AT nethajimunirathinam dimethyl224oxo2phenyl4hchromene57diyldioxydiacetatealessdenselypackedpolymorph
AT vembunagarajan dimethyl224oxo2phenyl4hchromene57diyldioxydiacetatealessdenselypackedpolymorph
AT jaswantbuckle dimethyl224oxo2phenyl4hchromene57diyldioxydiacetatealessdenselypackedpolymorph
AT sulochananagarajan dimethyl224oxo2phenyl4hchromene57diyldioxydiacetatealessdenselypackedpolymorph