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Dimethyl 2,2′-[(4-oxo-2-phenyl-4H-chromene-5,7-diyl)dioxy]diacetate: a less densely packed polymorph
The title molecule, C(21)H(18)O(8), crystallizes in two crystal polymorphs, see also Nallasivam, Nethaji, Vembu & Jaswant [Acta Cryst. (2009), E65, o312–o313]. The main difference between the two polymorphs is in the conformation of the oxomethylacetate groups with regard to the almost planar...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968320/ https://www.ncbi.nlm.nih.gov/pubmed/21581921 http://dx.doi.org/10.1107/S1600536809001019 |
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author | Nallasivam, Angannan Nethaji, Munirathinam Vembu, Nagarajan Jaswant, Buckle Sulochana, Nagarajan |
author_facet | Nallasivam, Angannan Nethaji, Munirathinam Vembu, Nagarajan Jaswant, Buckle Sulochana, Nagarajan |
author_sort | Nallasivam, Angannan |
collection | PubMed |
description | The title molecule, C(21)H(18)O(8), crystallizes in two crystal polymorphs, see also Nallasivam, Nethaji, Vembu & Jaswant [Acta Cryst. (2009), E65, o312–o313]. The main difference between the two polymorphs is in the conformation of the oxomethylacetate groups with regard to the almost planar [total puckering amplitude 0.047 (2) Å] chromene ring. In the title compound, the best planes of the oxomethylacetate groups through the non-H atoms are almost perpendicular to the chromene ring [making dihedral angles of 89.61 (6) and 80.59 (5)°], while in the second polymorph the molecules are close to planar. Both crystal structures are stabilized by C—H⋯O. |
format | Text |
id | pubmed-2968320 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29683202010-12-30 Dimethyl 2,2′-[(4-oxo-2-phenyl-4H-chromene-5,7-diyl)dioxy]diacetate: a less densely packed polymorph Nallasivam, Angannan Nethaji, Munirathinam Vembu, Nagarajan Jaswant, Buckle Sulochana, Nagarajan Acta Crystallogr Sect E Struct Rep Online Organic Papers The title molecule, C(21)H(18)O(8), crystallizes in two crystal polymorphs, see also Nallasivam, Nethaji, Vembu & Jaswant [Acta Cryst. (2009), E65, o312–o313]. The main difference between the two polymorphs is in the conformation of the oxomethylacetate groups with regard to the almost planar [total puckering amplitude 0.047 (2) Å] chromene ring. In the title compound, the best planes of the oxomethylacetate groups through the non-H atoms are almost perpendicular to the chromene ring [making dihedral angles of 89.61 (6) and 80.59 (5)°], while in the second polymorph the molecules are close to planar. Both crystal structures are stabilized by C—H⋯O. International Union of Crystallography 2009-01-14 /pmc/articles/PMC2968320/ /pubmed/21581921 http://dx.doi.org/10.1107/S1600536809001019 Text en © Nallasivam et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Nallasivam, Angannan Nethaji, Munirathinam Vembu, Nagarajan Jaswant, Buckle Sulochana, Nagarajan Dimethyl 2,2′-[(4-oxo-2-phenyl-4H-chromene-5,7-diyl)dioxy]diacetate: a less densely packed polymorph |
title | Dimethyl 2,2′-[(4-oxo-2-phenyl-4H-chromene-5,7-diyl)dioxy]diacetate: a less densely packed polymorph |
title_full | Dimethyl 2,2′-[(4-oxo-2-phenyl-4H-chromene-5,7-diyl)dioxy]diacetate: a less densely packed polymorph |
title_fullStr | Dimethyl 2,2′-[(4-oxo-2-phenyl-4H-chromene-5,7-diyl)dioxy]diacetate: a less densely packed polymorph |
title_full_unstemmed | Dimethyl 2,2′-[(4-oxo-2-phenyl-4H-chromene-5,7-diyl)dioxy]diacetate: a less densely packed polymorph |
title_short | Dimethyl 2,2′-[(4-oxo-2-phenyl-4H-chromene-5,7-diyl)dioxy]diacetate: a less densely packed polymorph |
title_sort | dimethyl 2,2′-[(4-oxo-2-phenyl-4h-chromene-5,7-diyl)dioxy]diacetate: a less densely packed polymorph |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968320/ https://www.ncbi.nlm.nih.gov/pubmed/21581921 http://dx.doi.org/10.1107/S1600536809001019 |
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