2-{1-[2-(Bis{2-[1-(5-chloro-2-hydroxy­phen­yl)ethyl­ideneamino]eth­yl}amino)­ethyl­iminio]eth­yl}-4-chloro­phenolate toluene hemisolvate

In the toluene hemisolvated tripodal tris­(2-amino­ethyl)amine Schiff base, C(30)H(33)Cl(3)N(4)O(3)·0.5C(7)H(8), one of the three imino N atoms is protonated, forming a hydrogen bond with the O atom at an adjacent benzene ring. The other two imino N atoms act as hydrogen-bond acceptors from phenolat...

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Detalles Bibliográficos
Autores principales: Lee, See Mun, Ali, Hapipah Mohd., Lo, Kong Mun, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968323/
https://www.ncbi.nlm.nih.gov/pubmed/21582001
http://dx.doi.org/10.1107/S1600536809002906
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author Lee, See Mun
Ali, Hapipah Mohd.
Lo, Kong Mun
Ng, Seik Weng
author_facet Lee, See Mun
Ali, Hapipah Mohd.
Lo, Kong Mun
Ng, Seik Weng
author_sort Lee, See Mun
collection PubMed
description In the toluene hemisolvated tripodal tris­(2-amino­ethyl)amine Schiff base, C(30)H(33)Cl(3)N(4)O(3)·0.5C(7)H(8), one of the three imino N atoms is protonated, forming a hydrogen bond with the O atom at an adjacent benzene ring. The other two imino N atoms act as hydrogen-bond acceptors from phenolate OH groups. The toluene solvent mol­ecule is disordered about a centre of inversion.
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spelling pubmed-29683232010-12-30 2-{1-[2-(Bis{2-[1-(5-chloro-2-hydroxy­phen­yl)ethyl­ideneamino]eth­yl}amino)­ethyl­iminio]eth­yl}-4-chloro­phenolate toluene hemisolvate Lee, See Mun Ali, Hapipah Mohd. Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers In the toluene hemisolvated tripodal tris­(2-amino­ethyl)amine Schiff base, C(30)H(33)Cl(3)N(4)O(3)·0.5C(7)H(8), one of the three imino N atoms is protonated, forming a hydrogen bond with the O atom at an adjacent benzene ring. The other two imino N atoms act as hydrogen-bond acceptors from phenolate OH groups. The toluene solvent mol­ecule is disordered about a centre of inversion. International Union of Crystallography 2009-01-28 /pmc/articles/PMC2968323/ /pubmed/21582001 http://dx.doi.org/10.1107/S1600536809002906 Text en © Lee et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lee, See Mun
Ali, Hapipah Mohd.
Lo, Kong Mun
Ng, Seik Weng
2-{1-[2-(Bis{2-[1-(5-chloro-2-hydroxy­phen­yl)ethyl­ideneamino]eth­yl}amino)­ethyl­iminio]eth­yl}-4-chloro­phenolate toluene hemisolvate
title 2-{1-[2-(Bis{2-[1-(5-chloro-2-hydroxy­phen­yl)ethyl­ideneamino]eth­yl}amino)­ethyl­iminio]eth­yl}-4-chloro­phenolate toluene hemisolvate
title_full 2-{1-[2-(Bis{2-[1-(5-chloro-2-hydroxy­phen­yl)ethyl­ideneamino]eth­yl}amino)­ethyl­iminio]eth­yl}-4-chloro­phenolate toluene hemisolvate
title_fullStr 2-{1-[2-(Bis{2-[1-(5-chloro-2-hydroxy­phen­yl)ethyl­ideneamino]eth­yl}amino)­ethyl­iminio]eth­yl}-4-chloro­phenolate toluene hemisolvate
title_full_unstemmed 2-{1-[2-(Bis{2-[1-(5-chloro-2-hydroxy­phen­yl)ethyl­ideneamino]eth­yl}amino)­ethyl­iminio]eth­yl}-4-chloro­phenolate toluene hemisolvate
title_short 2-{1-[2-(Bis{2-[1-(5-chloro-2-hydroxy­phen­yl)ethyl­ideneamino]eth­yl}amino)­ethyl­iminio]eth­yl}-4-chloro­phenolate toluene hemisolvate
title_sort 2-{1-[2-(bis{2-[1-(5-chloro-2-hydroxy­phen­yl)ethyl­ideneamino]eth­yl}amino)­ethyl­iminio]eth­yl}-4-chloro­phenolate toluene hemisolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968323/
https://www.ncbi.nlm.nih.gov/pubmed/21582001
http://dx.doi.org/10.1107/S1600536809002906
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AT ngseikweng 212bis215chloro2hydroxyphenylethylideneaminoethylaminoethyliminioethyl4chlorophenolatetoluenehemisolvate

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