(3RS)-S-[1-(3-Chloro­phen­yl)-2-oxopyr­roli­din-3-yl]thio­uronium bromide

In the title molecular salt, C(11)H(13)ClN(3)OS(+)·Br(−), the C—N bond lengths in the –S–C(NH(2))(2) fragment indicate partial double-bond character of these bonds. The constituent ions are connected by N—H⋯Br bridges into Z-shaped chains. The supra­molecular architecture of the structure can be des...

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Detalles Bibliográficos
Autores principales: Hanusek, Jiří, Sedlák, Miloš, Drabina, Pavel, Ružička, Aleš
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968325/
https://www.ncbi.nlm.nih.gov/pubmed/21582003
http://dx.doi.org/10.1107/S1600536809001603
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author Hanusek, Jiří
Sedlák, Miloš
Drabina, Pavel
Ružička, Aleš
author_facet Hanusek, Jiří
Sedlák, Miloš
Drabina, Pavel
Ružička, Aleš
author_sort Hanusek, Jiří
collection PubMed
description In the title molecular salt, C(11)H(13)ClN(3)OS(+)·Br(−), the C—N bond lengths in the –S–C(NH(2))(2) fragment indicate partial double-bond character of these bonds. The constituent ions are connected by N—H⋯Br bridges into Z-shaped chains. The supra­molecular architecture of the structure can be described by being composed of these chains inter­locked by additional C—H⋯Br short contacts. An intra­molecular N—H⋯O=C bridge, as well as weak C—H⋯O hydrogen bonds, are also present in the structure.
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spelling pubmed-29683252010-12-30 (3RS)-S-[1-(3-Chloro­phen­yl)-2-oxopyr­roli­din-3-yl]thio­uronium bromide Hanusek, Jiří Sedlák, Miloš Drabina, Pavel Ružička, Aleš Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecular salt, C(11)H(13)ClN(3)OS(+)·Br(−), the C—N bond lengths in the –S–C(NH(2))(2) fragment indicate partial double-bond character of these bonds. The constituent ions are connected by N—H⋯Br bridges into Z-shaped chains. The supra­molecular architecture of the structure can be described by being composed of these chains inter­locked by additional C—H⋯Br short contacts. An intra­molecular N—H⋯O=C bridge, as well as weak C—H⋯O hydrogen bonds, are also present in the structure. International Union of Crystallography 2009-01-28 /pmc/articles/PMC2968325/ /pubmed/21582003 http://dx.doi.org/10.1107/S1600536809001603 Text en © Hanusek et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hanusek, Jiří
Sedlák, Miloš
Drabina, Pavel
Ružička, Aleš
(3RS)-S-[1-(3-Chloro­phen­yl)-2-oxopyr­roli­din-3-yl]thio­uronium bromide
title (3RS)-S-[1-(3-Chloro­phen­yl)-2-oxopyr­roli­din-3-yl]thio­uronium bromide
title_full (3RS)-S-[1-(3-Chloro­phen­yl)-2-oxopyr­roli­din-3-yl]thio­uronium bromide
title_fullStr (3RS)-S-[1-(3-Chloro­phen­yl)-2-oxopyr­roli­din-3-yl]thio­uronium bromide
title_full_unstemmed (3RS)-S-[1-(3-Chloro­phen­yl)-2-oxopyr­roli­din-3-yl]thio­uronium bromide
title_short (3RS)-S-[1-(3-Chloro­phen­yl)-2-oxopyr­roli­din-3-yl]thio­uronium bromide
title_sort (3rs)-s-[1-(3-chloro­phen­yl)-2-oxopyr­roli­din-3-yl]thio­uronium bromide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968325/
https://www.ncbi.nlm.nih.gov/pubmed/21582003
http://dx.doi.org/10.1107/S1600536809001603
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AT sedlakmilos 3rss13chlorophenyl2oxopyrrolidin3ylthiouroniumbromide
AT drabinapavel 3rss13chlorophenyl2oxopyrrolidin3ylthiouroniumbromide
AT ruzickaales 3rss13chlorophenyl2oxopyrrolidin3ylthiouroniumbromide

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