3-O-Benzyl-6-O-benzoyl-1,2-O-isopropil­idene-5-C-nitro­methyl-a-d-glucofuran­ose

The title compound, C(24)H(27)NO(9), is one of the epimers of the Henry reaction of 3-O-benzyl-6-O-benzoyl-2-O-isopropyl­idene-a-d-glucofuran-5-one with nitro­methane. The conformation of the five membered rings is as expected from the precursor compound and the mol­ecule is folded with a dihedral a...

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Detalles Bibliográficos
Autores principales: Pampín, Begoña, Valencia, Laura, Estévez, Juan C., Estévez, Ramón J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968333/
https://www.ncbi.nlm.nih.gov/pubmed/21581936
http://dx.doi.org/10.1107/S1600536808043353
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author Pampín, Begoña
Valencia, Laura
Estévez, Juan C.
Estévez, Ramón J.
author_facet Pampín, Begoña
Valencia, Laura
Estévez, Juan C.
Estévez, Ramón J.
author_sort Pampín, Begoña
collection PubMed
description The title compound, C(24)H(27)NO(9), is one of the epimers of the Henry reaction of 3-O-benzyl-6-O-benzoyl-2-O-isopropyl­idene-a-d-glucofuran-5-one with nitro­methane. The conformation of the five membered rings is as expected from the precursor compound and the mol­ecule is folded with a dihedral angle of 51.4 (2)° between the aromatic rings. One O—H⋯O hydrogen bond and some intra­molecular and inter­molecular C—H⋯O inter­actions are observed in the structure.
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spelling pubmed-29683332010-12-30 3-O-Benzyl-6-O-benzoyl-1,2-O-isopropil­idene-5-C-nitro­methyl-a-d-glucofuran­ose Pampín, Begoña Valencia, Laura Estévez, Juan C. Estévez, Ramón J. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(24)H(27)NO(9), is one of the epimers of the Henry reaction of 3-O-benzyl-6-O-benzoyl-2-O-isopropyl­idene-a-d-glucofuran-5-one with nitro­methane. The conformation of the five membered rings is as expected from the precursor compound and the mol­ecule is folded with a dihedral angle of 51.4 (2)° between the aromatic rings. One O—H⋯O hydrogen bond and some intra­molecular and inter­molecular C—H⋯O inter­actions are observed in the structure. International Union of Crystallography 2009-01-17 /pmc/articles/PMC2968333/ /pubmed/21581936 http://dx.doi.org/10.1107/S1600536808043353 Text en © Pampín et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pampín, Begoña
Valencia, Laura
Estévez, Juan C.
Estévez, Ramón J.
3-O-Benzyl-6-O-benzoyl-1,2-O-isopropil­idene-5-C-nitro­methyl-a-d-glucofuran­ose
title 3-O-Benzyl-6-O-benzoyl-1,2-O-isopropil­idene-5-C-nitro­methyl-a-d-glucofuran­ose
title_full 3-O-Benzyl-6-O-benzoyl-1,2-O-isopropil­idene-5-C-nitro­methyl-a-d-glucofuran­ose
title_fullStr 3-O-Benzyl-6-O-benzoyl-1,2-O-isopropil­idene-5-C-nitro­methyl-a-d-glucofuran­ose
title_full_unstemmed 3-O-Benzyl-6-O-benzoyl-1,2-O-isopropil­idene-5-C-nitro­methyl-a-d-glucofuran­ose
title_short 3-O-Benzyl-6-O-benzoyl-1,2-O-isopropil­idene-5-C-nitro­methyl-a-d-glucofuran­ose
title_sort 3-o-benzyl-6-o-benzoyl-1,2-o-isopropil­idene-5-c-nitro­methyl-a-d-glucofuran­ose
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968333/
https://www.ncbi.nlm.nih.gov/pubmed/21581936
http://dx.doi.org/10.1107/S1600536808043353
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AT valencialaura 3obenzyl6obenzoyl12oisopropilidene5cnitromethyladglucofuranose
AT estevezjuanc 3obenzyl6obenzoyl12oisopropilidene5cnitromethyladglucofuranose
AT estevezramonj 3obenzyl6obenzoyl12oisopropilidene5cnitromethyladglucofuranose

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