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(R)-Di-tert-butyl 1,1′-binaphthyl-2,2′-dicarboxylate
The crystal structure of the title compound, C(30)H(30)O(4), comprises two crystallographically independent half-molecules which are completed by crystallographic twofold symmetry. The dihedral angles between the naphthalene ring planes are 85.83 (3) and 83.69 (3)° for the two molecules. The atoms...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968339/ https://www.ncbi.nlm.nih.gov/pubmed/21581860 http://dx.doi.org/10.1107/S1600536808044309 |
Sumario: | The crystal structure of the title compound, C(30)H(30)O(4), comprises two crystallographically independent half-molecules which are completed by crystallographic twofold symmetry. The dihedral angles between the naphthalene ring planes are 85.83 (3) and 83.69 (3)° for the two molecules. The atoms of the tert-butyl group of one molecule are disordered over two sets of sites with occupancies of 0.60:0.40. The crystal packing is achieved via π–π stacking interactions between the naphthyl groups of adjacent molecules, with a separation of 3.790 (1) Å between the centroids of the rings. |
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