4-(4-Pyridylamino)pyridinium perchlorate

In the title salt, C(10)H(10)N(3) (+)·ClO(4) (−), the 4-(4-pyridylamino)­pyridinium cations are linked into chains via N—H⋯N hydrogen bonding and into layers by C—H⋯π inter­actions [C⋯Cg = 3.3875 (19) Å]. Perchlorate ions are anchored to the layer motifs by N—H⋯O hydrogen bonding. The perchlorate an...

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Detalles Bibliográficos
Autores principales: Farnum, Gregory A., LaDuca, Robert L.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968340/
https://www.ncbi.nlm.nih.gov/pubmed/21582011
http://dx.doi.org/10.1107/S1600536809003353
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author Farnum, Gregory A.
LaDuca, Robert L.
author_facet Farnum, Gregory A.
LaDuca, Robert L.
author_sort Farnum, Gregory A.
collection PubMed
description In the title salt, C(10)H(10)N(3) (+)·ClO(4) (−), the 4-(4-pyridylamino)­pyridinium cations are linked into chains via N—H⋯N hydrogen bonding and into layers by C—H⋯π inter­actions [C⋯Cg = 3.3875 (19) Å]. Perchlorate ions are anchored to the layer motifs by N—H⋯O hydrogen bonding. The perchlorate anion was found to be disordered about a Cl—O axis, with two sites, each of equal occupancy, being resolved for the three remaining O atoms.
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spelling pubmed-29683402010-12-30 4-(4-Pyridylamino)pyridinium perchlorate Farnum, Gregory A. LaDuca, Robert L. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(10)H(10)N(3) (+)·ClO(4) (−), the 4-(4-pyridylamino)­pyridinium cations are linked into chains via N—H⋯N hydrogen bonding and into layers by C—H⋯π inter­actions [C⋯Cg = 3.3875 (19) Å]. Perchlorate ions are anchored to the layer motifs by N—H⋯O hydrogen bonding. The perchlorate anion was found to be disordered about a Cl—O axis, with two sites, each of equal occupancy, being resolved for the three remaining O atoms. International Union of Crystallography 2009-01-31 /pmc/articles/PMC2968340/ /pubmed/21582011 http://dx.doi.org/10.1107/S1600536809003353 Text en © Farnum and LaDuca 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Farnum, Gregory A.
LaDuca, Robert L.
4-(4-Pyridylamino)pyridinium perchlorate
title 4-(4-Pyridylamino)pyridinium perchlorate
title_full 4-(4-Pyridylamino)pyridinium perchlorate
title_fullStr 4-(4-Pyridylamino)pyridinium perchlorate
title_full_unstemmed 4-(4-Pyridylamino)pyridinium perchlorate
title_short 4-(4-Pyridylamino)pyridinium perchlorate
title_sort 4-(4-pyridylamino)pyridinium perchlorate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968340/
https://www.ncbi.nlm.nih.gov/pubmed/21582011
http://dx.doi.org/10.1107/S1600536809003353
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