[(2-Morpholinoeth­yl)(2-pyridylmethyl­ene)amine]dithio­cyanato­zinc(II)

The title compound, [Zn(NCS)(2)(C(12)H(17)N(3)O)], was prepared by the reaction of zinc acetate with pyridine-2-carbaldehyde, 2-morpholinoethyl­amine and ammonium thio­cyanate in an ethanol solution. The Zn(II) atom is five coordinate with a distorted trigonal–bipyramidal geometry, coordinating with...

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Detalles Bibliográficos
Autor principal: Cai, Bang-Hong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968346/
https://www.ncbi.nlm.nih.gov/pubmed/21581757
http://dx.doi.org/10.1107/S1600536808044061
Descripción
Sumario:The title compound, [Zn(NCS)(2)(C(12)H(17)N(3)O)], was prepared by the reaction of zinc acetate with pyridine-2-carbaldehyde, 2-morpholinoethyl­amine and ammonium thio­cyanate in an ethanol solution. The Zn(II) atom is five coordinate with a distorted trigonal–bipyramidal geometry, coordinating with three N atoms of the Schiff base (2-morpholinoeth­yl)(2-pyridylmethyl­idene)amine and two N atoms from two thio­cyanate ligands. The morpholine ring adopts a chair configuration.

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