[(2-Morpholinoeth­yl)(2-pyridylmethyl­ene)amine]dithio­cyanato­zinc(II)

The title compound, [Zn(NCS)(2)(C(12)H(17)N(3)O)], was prepared by the reaction of zinc acetate with pyridine-2-carbaldehyde, 2-morpholinoethyl­amine and ammonium thio­cyanate in an ethanol solution. The Zn(II) atom is five coordinate with a distorted trigonal–bipyramidal geometry, coordinating with...

Descripción completa

Detalles Bibliográficos
Autor principal: Cai, Bang-Hong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968346/
https://www.ncbi.nlm.nih.gov/pubmed/21581757
http://dx.doi.org/10.1107/S1600536808044061
_version_ 1782189847593615360
author Cai, Bang-Hong
author_facet Cai, Bang-Hong
author_sort Cai, Bang-Hong
collection PubMed
description The title compound, [Zn(NCS)(2)(C(12)H(17)N(3)O)], was prepared by the reaction of zinc acetate with pyridine-2-carbaldehyde, 2-morpholinoethyl­amine and ammonium thio­cyanate in an ethanol solution. The Zn(II) atom is five coordinate with a distorted trigonal–bipyramidal geometry, coordinating with three N atoms of the Schiff base (2-morpholinoeth­yl)(2-pyridylmethyl­idene)amine and two N atoms from two thio­cyanate ligands. The morpholine ring adopts a chair configuration.
format Text
id pubmed-2968346
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29683462010-12-30 [(2-Morpholinoeth­yl)(2-pyridylmethyl­ene)amine]dithio­cyanato­zinc(II) Cai, Bang-Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Zn(NCS)(2)(C(12)H(17)N(3)O)], was prepared by the reaction of zinc acetate with pyridine-2-carbaldehyde, 2-morpholinoethyl­amine and ammonium thio­cyanate in an ethanol solution. The Zn(II) atom is five coordinate with a distorted trigonal–bipyramidal geometry, coordinating with three N atoms of the Schiff base (2-morpholinoeth­yl)(2-pyridylmethyl­idene)amine and two N atoms from two thio­cyanate ligands. The morpholine ring adopts a chair configuration. International Union of Crystallography 2009-01-08 /pmc/articles/PMC2968346/ /pubmed/21581757 http://dx.doi.org/10.1107/S1600536808044061 Text en © Bang-Hong Cai 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cai, Bang-Hong
[(2-Morpholinoeth­yl)(2-pyridylmethyl­ene)amine]dithio­cyanato­zinc(II)
title [(2-Morpholinoeth­yl)(2-pyridylmethyl­ene)amine]dithio­cyanato­zinc(II)
title_full [(2-Morpholinoeth­yl)(2-pyridylmethyl­ene)amine]dithio­cyanato­zinc(II)
title_fullStr [(2-Morpholinoeth­yl)(2-pyridylmethyl­ene)amine]dithio­cyanato­zinc(II)
title_full_unstemmed [(2-Morpholinoeth­yl)(2-pyridylmethyl­ene)amine]dithio­cyanato­zinc(II)
title_short [(2-Morpholinoeth­yl)(2-pyridylmethyl­ene)amine]dithio­cyanato­zinc(II)
title_sort [(2-morpholinoeth­yl)(2-pyridylmethyl­ene)amine]dithio­cyanato­zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968346/
https://www.ncbi.nlm.nih.gov/pubmed/21581757
http://dx.doi.org/10.1107/S1600536808044061
work_keys_str_mv AT caibanghong 2morpholinoethyl2pyridylmethyleneaminedithiocyanatozincii

Ejemplares similares