trans-Bis(acetonitrile-κN)tetra­aqua­cobalt(II) tetra­chloridocobaltate(II)

In the title complex, [Co(CH(3)CN)(2)(H(2)O)(4)][CoCl(4)], the Co(II) ions are octa­hedrally coordinated in the cation, with trans-disposed acetonitrile ligands, and tetra­hedrally coordinated in the anion. An extensive network of O—H(water)⋯Cl hydrogen bonds between cations and anions connects the...

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Detalles Bibliográficos
Autores principales: Patroniak, Violetta, Kubicki, Maciej
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968350/
https://www.ncbi.nlm.nih.gov/pubmed/21581780
http://dx.doi.org/10.1107/S1600536809000750
Descripción
Sumario:In the title complex, [Co(CH(3)CN)(2)(H(2)O)(4)][CoCl(4)], the Co(II) ions are octa­hedrally coordinated in the cation, with trans-disposed acetonitrile ligands, and tetra­hedrally coordinated in the anion. An extensive network of O—H(water)⋯Cl hydrogen bonds between cations and anions connects the ions into a three-dimensional network. The Co—Cl distances correlate with the number of hydrogen bonds accepted by the Cl atoms.

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