trans-Bis(acetonitrile-κN)tetra­aqua­cobalt(II) tetra­chloridocobaltate(II)

In the title complex, [Co(CH(3)CN)(2)(H(2)O)(4)][CoCl(4)], the Co(II) ions are octa­hedrally coordinated in the cation, with trans-disposed acetonitrile ligands, and tetra­hedrally coordinated in the anion. An extensive network of O—H(water)⋯Cl hydrogen bonds between cations and anions connects the...

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Detalles Bibliográficos
Autores principales: Patroniak, Violetta, Kubicki, Maciej
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968350/
https://www.ncbi.nlm.nih.gov/pubmed/21581780
http://dx.doi.org/10.1107/S1600536809000750
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author Patroniak, Violetta
Kubicki, Maciej
author_facet Patroniak, Violetta
Kubicki, Maciej
author_sort Patroniak, Violetta
collection PubMed
description In the title complex, [Co(CH(3)CN)(2)(H(2)O)(4)][CoCl(4)], the Co(II) ions are octa­hedrally coordinated in the cation, with trans-disposed acetonitrile ligands, and tetra­hedrally coordinated in the anion. An extensive network of O—H(water)⋯Cl hydrogen bonds between cations and anions connects the ions into a three-dimensional network. The Co—Cl distances correlate with the number of hydrogen bonds accepted by the Cl atoms.
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spelling pubmed-29683502010-12-30 trans-Bis(acetonitrile-κN)tetra­aqua­cobalt(II) tetra­chloridocobaltate(II) Patroniak, Violetta Kubicki, Maciej Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Co(CH(3)CN)(2)(H(2)O)(4)][CoCl(4)], the Co(II) ions are octa­hedrally coordinated in the cation, with trans-disposed acetonitrile ligands, and tetra­hedrally coordinated in the anion. An extensive network of O—H(water)⋯Cl hydrogen bonds between cations and anions connects the ions into a three-dimensional network. The Co—Cl distances correlate with the number of hydrogen bonds accepted by the Cl atoms. International Union of Crystallography 2009-01-10 /pmc/articles/PMC2968350/ /pubmed/21581780 http://dx.doi.org/10.1107/S1600536809000750 Text en © Patroniak and Kubicki 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Patroniak, Violetta
Kubicki, Maciej
trans-Bis(acetonitrile-κN)tetra­aqua­cobalt(II) tetra­chloridocobaltate(II)
title trans-Bis(acetonitrile-κN)tetra­aqua­cobalt(II) tetra­chloridocobaltate(II)
title_full trans-Bis(acetonitrile-κN)tetra­aqua­cobalt(II) tetra­chloridocobaltate(II)
title_fullStr trans-Bis(acetonitrile-κN)tetra­aqua­cobalt(II) tetra­chloridocobaltate(II)
title_full_unstemmed trans-Bis(acetonitrile-κN)tetra­aqua­cobalt(II) tetra­chloridocobaltate(II)
title_short trans-Bis(acetonitrile-κN)tetra­aqua­cobalt(II) tetra­chloridocobaltate(II)
title_sort trans-bis(acetonitrile-κn)tetra­aqua­cobalt(ii) tetra­chloridocobaltate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968350/
https://www.ncbi.nlm.nih.gov/pubmed/21581780
http://dx.doi.org/10.1107/S1600536809000750
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AT kubickimaciej transbisacetonitrilekntetraaquacobaltiitetrachloridocobaltateii

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