catena-Poly[[bis­(5-chloro-2-nitro­benzoato)copper(II)]-bis­(μ-5-chloro-2-nitro­benzoato)]

In the title compound, [Cu(2)(C(7)H(3)ClNO(4))(4)](n), the coordination geometry around each Cu(II) ion is distorted square-pyramidal. The CuO(5) coordination is formed by five O atoms from the carboxyl­ate groups of five 5-chloro-2-nitro­benzoate ligands. This coordination leads to the formation of...

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Detalles Bibliográficos
Autores principales: Lim, Eng Khoon, Teoh, Siang Guan, Razak, Ibrahim Abdul, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968352/
https://www.ncbi.nlm.nih.gov/pubmed/21581807
http://dx.doi.org/10.1107/S1600536809001895
Descripción
Sumario:In the title compound, [Cu(2)(C(7)H(3)ClNO(4))(4)](n), the coordination geometry around each Cu(II) ion is distorted square-pyramidal. The CuO(5) coordination is formed by five O atoms from the carboxyl­ate groups of five 5-chloro-2-nitro­benzoate ligands. This coordination leads to the formation of centrosymmetric binuclear units which are edge-shared, forming a linear chain along the a axis, with the Cu(II) ions alternately separated by 2.5891 (4) and 3.1763 (4) Å. The chains are inter­connected into a three-dimensional network by C—H⋯O inter­actions.