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catena-Poly[[bis(5-chloro-2-nitrobenzoato)copper(II)]-bis(μ-5-chloro-2-nitrobenzoato)]
In the title compound, [Cu(2)(C(7)H(3)ClNO(4))(4)](n), the coordination geometry around each Cu(II) ion is distorted square-pyramidal. The CuO(5) coordination is formed by five O atoms from the carboxylate groups of five 5-chloro-2-nitrobenzoate ligands. This coordination leads to the formation of...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968352/ https://www.ncbi.nlm.nih.gov/pubmed/21581807 http://dx.doi.org/10.1107/S1600536809001895 |
| _version_ | 1782189849318522880 |
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| author | Lim, Eng Khoon Teoh, Siang Guan Razak, Ibrahim Abdul Fun, Hoong-Kun |
| author_facet | Lim, Eng Khoon Teoh, Siang Guan Razak, Ibrahim Abdul Fun, Hoong-Kun |
| author_sort | Lim, Eng Khoon |
| collection | PubMed |
| description | In the title compound, [Cu(2)(C(7)H(3)ClNO(4))(4)](n), the coordination geometry around each Cu(II) ion is distorted square-pyramidal. The CuO(5) coordination is formed by five O atoms from the carboxylate groups of five 5-chloro-2-nitrobenzoate ligands. This coordination leads to the formation of centrosymmetric binuclear units which are edge-shared, forming a linear chain along the a axis, with the Cu(II) ions alternately separated by 2.5891 (4) and 3.1763 (4) Å. The chains are interconnected into a three-dimensional network by C—H⋯O interactions. |
| format | Text |
| id | pubmed-2968352 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29683522010-12-30 catena-Poly[[bis(5-chloro-2-nitrobenzoato)copper(II)]-bis(μ-5-chloro-2-nitrobenzoato)] Lim, Eng Khoon Teoh, Siang Guan Razak, Ibrahim Abdul Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(2)(C(7)H(3)ClNO(4))(4)](n), the coordination geometry around each Cu(II) ion is distorted square-pyramidal. The CuO(5) coordination is formed by five O atoms from the carboxylate groups of five 5-chloro-2-nitrobenzoate ligands. This coordination leads to the formation of centrosymmetric binuclear units which are edge-shared, forming a linear chain along the a axis, with the Cu(II) ions alternately separated by 2.5891 (4) and 3.1763 (4) Å. The chains are interconnected into a three-dimensional network by C—H⋯O interactions. International Union of Crystallography 2009-01-23 /pmc/articles/PMC2968352/ /pubmed/21581807 http://dx.doi.org/10.1107/S1600536809001895 Text en © Lim et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Lim, Eng Khoon Teoh, Siang Guan Razak, Ibrahim Abdul Fun, Hoong-Kun catena-Poly[[bis(5-chloro-2-nitrobenzoato)copper(II)]-bis(μ-5-chloro-2-nitrobenzoato)] |
| title |
catena-Poly[[bis(5-chloro-2-nitrobenzoato)copper(II)]-bis(μ-5-chloro-2-nitrobenzoato)] |
| title_full |
catena-Poly[[bis(5-chloro-2-nitrobenzoato)copper(II)]-bis(μ-5-chloro-2-nitrobenzoato)] |
| title_fullStr |
catena-Poly[[bis(5-chloro-2-nitrobenzoato)copper(II)]-bis(μ-5-chloro-2-nitrobenzoato)] |
| title_full_unstemmed |
catena-Poly[[bis(5-chloro-2-nitrobenzoato)copper(II)]-bis(μ-5-chloro-2-nitrobenzoato)] |
| title_short |
catena-Poly[[bis(5-chloro-2-nitrobenzoato)copper(II)]-bis(μ-5-chloro-2-nitrobenzoato)] |
| title_sort | catena-poly[[bis(5-chloro-2-nitrobenzoato)copper(ii)]-bis(μ-5-chloro-2-nitrobenzoato)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968352/ https://www.ncbi.nlm.nih.gov/pubmed/21581807 http://dx.doi.org/10.1107/S1600536809001895 |
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