A second modification of poly[diaquadi-μ-citrato(3−)-trizinc(II)]

A second modification of the zinc(II) coordination polymer with citric acid, [Zn(3)(C(6)H(5)O(7))(2)(H(2)O)(2)](n) or [Zn(citrate)(2)(H(2)O)(2)], has been synthesized under hydro­thermal conditions by reacting zinc acetate with citric acid. The structure contains two unique Zn atoms, one with a dist...

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Detalles Bibliográficos
Autores principales: Li, Xiang-He, Chen, Wei-Lin, Wang, En-Bo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968354/
https://www.ncbi.nlm.nih.gov/pubmed/21581787
http://dx.doi.org/10.1107/S1600536808028456
Descripción
Sumario:A second modification of the zinc(II) coordination polymer with citric acid, [Zn(3)(C(6)H(5)O(7))(2)(H(2)O)(2)](n) or [Zn(citrate)(2)(H(2)O)(2)], has been synthesized under hydro­thermal conditions by reacting zinc acetate with citric acid. The structure contains two unique Zn atoms, one with a distorted octa­hedral coordination and located on an inversion centre, and one with a distorted tetra­hedral coordination. The ZnO(6) and ZnO(4) units are linked into layers extending parallel to (010).

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