(E)-N′-(4-Pyridylmethyl­ene)-4-(8-quinol­yl­oxy)butanohydrazide 0.25-hydrate

The asymmetric unit of the title compound, C(19)H(18)N(4)O(2)·0.25H(2)O, contains two organic mol­ecules and a solvent water mol­ecule with 50% occupancy. The two molecules differ in their conformations: in one mol­ecule it is (+)gauche-trans-trans-(+)gauche-trans, whereas in the other it is (−)gauc...

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Detalles Bibliográficos
Autores principales: Chen, Min-E, Li, Jia-Ming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968356/
https://www.ncbi.nlm.nih.gov/pubmed/21581905
http://dx.doi.org/10.1107/S160053680900110X
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author Chen, Min-E
Li, Jia-Ming
author_facet Chen, Min-E
Li, Jia-Ming
author_sort Chen, Min-E
collection PubMed
description The asymmetric unit of the title compound, C(19)H(18)N(4)O(2)·0.25H(2)O, contains two organic mol­ecules and a solvent water mol­ecule with 50% occupancy. The two molecules differ in their conformations: in one mol­ecule it is (+)gauche-trans-trans-(+)gauche-trans, whereas in the other it is (−)gauche-trans-trans-(−)gauche-trans. The dihedral angles between the pyridine ring and the quinoline ring system are 67.4 (3) and 68.0 (2)°. Mol­ecules are linked into a supra­molecular two-dimensional array via N—H⋯N hydrogen bonds, with each partially occupied water mol­ecule connected via an O—H⋯O hydrogen bond. C—H⋯O inter­actions are also present.
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spelling pubmed-29683562010-12-30 (E)-N′-(4-Pyridylmethyl­ene)-4-(8-quinol­yl­oxy)butanohydrazide 0.25-hydrate Chen, Min-E Li, Jia-Ming Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(19)H(18)N(4)O(2)·0.25H(2)O, contains two organic mol­ecules and a solvent water mol­ecule with 50% occupancy. The two molecules differ in their conformations: in one mol­ecule it is (+)gauche-trans-trans-(+)gauche-trans, whereas in the other it is (−)gauche-trans-trans-(−)gauche-trans. The dihedral angles between the pyridine ring and the quinoline ring system are 67.4 (3) and 68.0 (2)°. Mol­ecules are linked into a supra­molecular two-dimensional array via N—H⋯N hydrogen bonds, with each partially occupied water mol­ecule connected via an O—H⋯O hydrogen bond. C—H⋯O inter­actions are also present. International Union of Crystallography 2009-01-14 /pmc/articles/PMC2968356/ /pubmed/21581905 http://dx.doi.org/10.1107/S160053680900110X Text en © Chen and Li 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chen, Min-E
Li, Jia-Ming
(E)-N′-(4-Pyridylmethyl­ene)-4-(8-quinol­yl­oxy)butanohydrazide 0.25-hydrate
title (E)-N′-(4-Pyridylmethyl­ene)-4-(8-quinol­yl­oxy)butanohydrazide 0.25-hydrate
title_full (E)-N′-(4-Pyridylmethyl­ene)-4-(8-quinol­yl­oxy)butanohydrazide 0.25-hydrate
title_fullStr (E)-N′-(4-Pyridylmethyl­ene)-4-(8-quinol­yl­oxy)butanohydrazide 0.25-hydrate
title_full_unstemmed (E)-N′-(4-Pyridylmethyl­ene)-4-(8-quinol­yl­oxy)butanohydrazide 0.25-hydrate
title_short (E)-N′-(4-Pyridylmethyl­ene)-4-(8-quinol­yl­oxy)butanohydrazide 0.25-hydrate
title_sort (e)-n′-(4-pyridylmethyl­ene)-4-(8-quinol­yl­oxy)butanohydrazide 0.25-hydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968356/
https://www.ncbi.nlm.nih.gov/pubmed/21581905
http://dx.doi.org/10.1107/S160053680900110X
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